(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 135620-04-1

Ref. 3D-FB29346

Produktinformation

• Name: (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
• Synonyme: (S,S)-Jacobsen's catalyst manganese(III) chloride complex
• Marke: Biosynth
• Beschreibung: The preparation of racemic N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is carried out by the reaction of salicyaldehyde with manganese dioxide in acetonitrile. The mixture is heated to reflux for 3 hours. The product is purified by recrystallization from hot acetonitrile and then purified again by preparative thin layer chromatography using a chiral stationary phase. The product is obtained as a white powder in an overall yield of 52%.The synthesis of (R)-(-)-N-(3,5-Di-tert-butylsalicyl

Chemische Eigenschaften

• Molekulargewicht: 635.2 g/mol
• Formel: C₃₆H₅₂ClMnN₂O₂
• Farbe/Form: Powder