1-Methyl-4-(sulfinylamino)benzene
CAS: 15795-42-3
Ref. 3D-FM133909
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Produktinformation
Name:
1-Methyl-4-(sulfinylamino)benzene
Synonyme:
- benzene
- 1-methyl-4-(sulfinylamino)-
- Benzenamine, 4-methyl-N-sulfinyl-
- 4-methyl-N-sulfinylaniline
Beschreibung:
1-Methyl-4-(sulfinylamino)benzene is a molecule that contains a hydroxyl group. It is an isomer of 1-methyl-4-nitrobenzene. The hydroxyl group in 1-methyl-4-(sulfinylamino)benzene reacts with the sulfinamide group to form a cyclometallated intermediate. This reaction has an activation energy of 32 kcal/mol, which is higher than the activation energies for other reactions involving nucleophilic substitution. The nmr spectra shows this product as having two methyl groups, which are present on either side of the sulfinamide group. Kinetic studies show that the conformational change in this molecule can be enhanced by adding ligands to it.
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Marke:
Biosynth
Langzeitlagerung:
Hinweise:
Chemische Eigenschaften
Molekulargewicht:
153.2 g/mol
Formel:
C7H7NOS
Reinheit:
Min. 95%
InChl:
InChI=1S/C7H7NOS/c1-6-2-4-7(5-3-6)8-10-9/h2-5H,1H3
InChI Key:
InChIKey=KLHMRBYLBVCGDT-UHFFFAOYSA-N
SMILES:
Cc1ccc(N=S=O)cc1
MDL:
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