(S)-Ru(OAc)2(BINAP)

CAS: 261948-85-0

Ref. 3D-FR164040

Produktinformation

• Name: (S)-Ru(OAc)2(BINAP)
• Synonyme: Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-

Beschreibung

The mechanism of the Ru-catalyzed hydrogenation of 2-butynoic acid to butyric acid is a three-step process. The first step involves the addition of a proton and an electron from H2O to the substrate, forming a carbonyl compound. The second step involves the transfer of a hydride ion from Ru to the carbonyl compound, forming an alcohol. The third step involves the elimination of H2O with simultaneous formation of a double bond and release of CO2. This reaction has been shown to be catalytic in acidic conditions, recycling Ru and producing no emissions. The active catalyst is (S)-Ru(OAc)2(BINAP). The major functionalities are mesoporous silica and tiglic acid, which enhance reactivity by providing pairwise interactions between substrates and catalyst.

• Marke: Biosynth

Chemische Eigenschaften

• Molekulargewicht: 841.83 g/mol
• Formel: C₄₈H₃₈O₄P₂Ru
• Reinheit: Min. 95%