Produktinformation
Name:ETHYNYLTRIETHYLSILANE
Synonyme:
- TRIETHYLSILYLACETYLENE
Marke:Gelest
Beschreibung:Alkynylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Ethynyltriethylsilane; Triethylsilylacetylene
More stable protected acetylene useful in Sonogashira reactions.Reacts with enol silyl ethers to form α,α-bis-trans-&beta-triethylsilylethenyl ketonesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Ethynyltriethylsilane; Triethylsilylacetylene
More stable protected acetylene useful in Sonogashira reactions.Reacts with enol silyl ethers to form α,α-bis-trans-&beta-triethylsilylethenyl ketonesExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
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Chemische Eigenschaften
Molekulargewicht:140.3
Formel:C8H16Si
Reinheit:97%
Farbe/Form:Straw Liquid