VINYLTRIMETHYLSILANE

CAS: 754-05-2

Ref. 3H-SIV9250.0

Produktinformation

• Name: VINYLTRIMETHYLSILANE
• Synonyme: (Trimethylsilyl)ethene, (Trimethylsilyl)ethylene, Ethenyltrimethylsilane, Nsc 93553, Silane, Trimethylvinyl, Trimethyl(vinyl)silane, Trimethylvinylsilan, Trimethylvinylsilane, Trimetilvinilsilano, Vinyltrimethylsilane, W 139
• CAS: 754-05-2

Beschreibung

Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Vinyltrimethylsilane; Ethenyltrimethylsilane; Trimethylsilylethene; Trimethylvinylsilane
Viscosity, 20 °C: 0.5 cStΔHcomb: 4,133 kJ/molΔHfus: 7.7 kJ/molCopolymerization parameters- e,Q: 0.04, 0.029Forms polymers which can be fabricated into oxygen enrichment membranesPolymerization catalyzed by alkyllithium compoundsReacts w/ azides to form trimethylsilyl-substituted aziridinesUndergoes Heck coupling to (E)-β-substituted vinyltrimethylsilanes, which can then be cross-coupled furtherExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

• Marke: Gelest

Chemische Eigenschaften

• Molekulargewicht: 100.24
• Formel: C₅H₁₂Si
• Reinheit: 97%
• Farbe/Form: Straw Liquid