[1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride

CAS: 15629-92-2

Ref. TR-B430353

Produktinformation

• Name: [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride
• Synonyme: (1,3-Bis(diphenylphosphino)propane)dichloronickel, 1,3-Bis(diphenylphosphino)nickel Dichloride, Dichloro[1,3-bis(diphenylphosphino)propane]nickel, Nickel 1,3-Bis(diphenylphosphino)propane Dichloride, (1,3-dppp)NiCl2
• Marke: TRC

Beschreibung

Applications [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins.
References Li, J., et al.: J. Polym. Res., 19, 1-9 (2012); Yamamoto, T., et al.: Tetrahedron Lett., 42, 8653-8656 (2001);

Chemische Eigenschaften

• Molekulargewicht: 542.04
• Formel: C₂₇H₂₆Cl₂NiP₂
• Farbe/Form: Neat
• InChl: InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
• SMILES: [Cl-].[Cl-].[Ni+2].c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1