1,4-Cyclohexadiene Monoepoxide

CAS: 6253-27-6

Ref. TR-C989533

Produktinformation

• Name: 1,4-Cyclohexadiene Monoepoxide
• Synonyme: 1,2-Epoxy-4-cyclohexene, 1,4-Cyclohexadiene 1,2-Oxide, 1,4-Cyclohexadiene Monoxide, 4,5-Epoxy-1-cyclohexene, 4,5-Epoxycyclohexene, Cyclohexene 4,5-Epoxide, NSC 116459, NSC 196239, 1,4-Cyclohexadiene 1,2-oxide, Cyclohexene 4,5-epoxide, 7-Oxabicyclo[4.1.0]hept-3-ene

Beschreibung

Stability Smelly, Volatile product
Applications 1,4-Cyclohexadiene Monoepoxide is a synthetic intermediate. It is used as a reactant in the enantioselective formal synthesis of 4-demethoxydaunomycin. Also used in the asymmetric synthesis of β-amino and vicinal amino alcohols.
References Sekine, A., et al.: Tetrahedron, 58, 75 (2002); Carree, F., et al.: Org. Lett., 7, 1023 (2005); Arai, K., et al.: J. Am. Chem. Soc., 129, 8103 (2007);

• Marke: TRC

Chemische Eigenschaften

• Molekulargewicht: 96.13
• Formel: C₆H₈O
• Farbe/Form: Neat
• InChl: InChI=1S/C6H8O/c1-2-4-6-5(3-1)7-6/h1-2,5-6H,3-4H2
• InChI Key: InChIKey=QLQSJLSVPZCPPZ-UHFFFAOYSA-N
• SMILES: C1=CCC2OC2C1