Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS: 12354-84-6

Ref. TR-D438770

Produktinformation

• Name: Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
• Synonyme: (Pentamethylcyclopentadienyl)iridium dichloride dimer, (Ir(Cp*)Cl₂)₂, (Pentamethylcyclopentadienyl)iridium(III)Dichloride Dimer, (η⁵-Pentamethylcyclopentadienyl)iridium dichloride dimer, 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, iridium complex, Bis((μ-chloro)chloro(η⁵-pentamethylcyclopentadienyl)iridium), Bis(chloro(μ₂-chloro)(η⁵-pentamethylcyclopentadienyl)iridium), Bis(dichloro(η⁵-pentamethylcyclopentadienyl)iridium), Bis(dichloro(η⁵-η-pentamethylcyclopentadienyl)iridium), Bis(pentamethylcyclopentadiene)tetrachlorodiiridium, Bis(pentamethylcyclopentadienyliridium dichloride), Bis(μ-chloro)bis[chloro(η⁵-pentamethylcyclopentadienyl)iridium], Bis[dichloro(pentamethylcyclopentadienyl)iridium], Di-μ-chlorobis(chloro(η⁵-pentamethylcyclopentadienyl)iridium), Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)diiridium, Dichloro(pentamethylcyclopentadienyl)iridium dimer, Dichlorobis(μ₂-chloro)bis(η⁵-pentamethylcyclopentadienyl)diiridium, Dichlorodi-μ-chlorobis(η⁵-pentamethylcyclopentadienyl)diiridium, Dichloropentamethylcyclopentadienyliridiumdimer, Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-, Pentamethylcyclopentadienyl)iridium(III) chloride dimer, Pentamethylcyclopentadienyliridium(III) chloride,dimer, Pentamethylcyclopentadienyliridium(III) dichloride dimer, Tetrachlorobis(pentamethylcyclopentadienyl)diiridium, Tetrachlorobis(η⁵-pentamethylcyclopentadienyl)diiridium, [Cp*IrCl₂]₂
• CAS: 12354-84-6

Beschreibung

Applications Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is commonly found to be used as a catalyst in reactions, and the synthesis oxidative arylation with indoles, azobenzene derivatives., and ortho-​alkynylated arylalkylamines.
References Li, G., et al.: Org. Lett., 20, 2454-58 (2018); Tindall, D.J., et al.: J. Am. Chem. Soc., 140, 1884-93 (2018); Chen, X., et al.: Org. Lett., 20, 1171-74 (2018);

• Marke: TRC

Chemische Eigenschaften

• Molekulargewicht: 796.7
• Formel: C₂₀H₃₀Cl₄Ir₂
• Farbe/Form: Neat
• InChl: InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4
• SMILES: C[C]1C(C)=C(C)C(C)=C1C.C[C]1C(C)=C(C)C(C)=C1C.[Cl-].[Cl-].[Cl-].[Cl-].[Ir+2].[Ir+2]