(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol

CAS: 137365-09-4

Ref. TR-D479455

Produktinformation

• Name: (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
• Synonyme: (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, (4R,5R)-2,2-Dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, (4R-trans)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol
• Marke: TRC
• Beschreibung: Applications (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.References Seebach, D., et al.: Ange. Chem. Inter. Ed., 40, 92, (20010

Chemische Eigenschaften

• Molekulargewicht: 666.802
• Formel: C₄₇H₃₈O₄
• Farbe/Form: Neat
• InChl: InChI=1S/C47H38O4/c1-45(2)50-43(46(48,39-23-19-31-11-3-7-15-35(31)27-39)40-24-20-32-12-4-8-16-36(32)28-40)44(51-45)47(49,41-25-21-33-13-5-9-17-37(33)29-41)42-26-22-34-14-6-10-18-38(34)30-42/h3-30,43-44,48-49H,1-2H3/t43-,44-/m1/s1
• InChI Key: InChIKey=QWADMRIAKWGVBF-NDOUMJCMSA-N
• SMILES: CC1(C)O[C@@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)[C@H](C(O)(c2ccc3ccccc3c2)c2ccc3ccccc3c2)O1