(-)-B-Methoxydiisopinocampheylborane hydrate

CAS: 85134-98-1

Ref. TR-M269740

Produktinformation

• Name: (-)-B-Methoxydiisopinocampheylborane hydrate
• Synonyme: (-)-B-Methoxydiisopinocampheylborane, (-)-Diisopinocampheylmethoxyborane, (-)-Ipc2B(OMe), (-)-Methoxydiisopinocampheylborane, Methoxybis((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
• Marke: TRC
• Beschreibung: Applications (-)-B-Methoxydiisopinocampheylborane hydrate is an intermediate used in the synthesis of homoallylic alcohol's and several complex natural products.References Mishra, V. K., et al.: J. Org. Chem., 81, 9728 (2016); Jonnalagadda, S. C., et al.: e-EROS Encyclopedia of Reagents for Organic Synthesis 1, (2009); Bailey, A. M., et al.: Angew. Chem. Int. Ed., 55, 639 (2016)

Chemische Eigenschaften

• Molekulargewicht: 316.33 + x(18.02)
• Formel: C₂₁H₃₇BO·x(H₂O)
• Farbe/Form: Neat
• InChl: InChI=1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14+,15+,16-,17-,18-,19-/m1/s1
• InChI Key: InChIKey=IAQXEQYLQNNXJC-IYGAUZJWSA-N
• SMILES: COB(C1CC2CC(C1C)C2(C)C)[C@@H]1C[C@@H]2C[C@H](C1C)C2(C)C