(2R,3S)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid tert-Butyl Ester

CAS: 112741-49-8

Ref. TR-O869970

Produktinformation

• Name: (2R,3S)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid tert-Butyl Ester
• Synonyme: (2R-cis)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid 1,1-Dimethylethyl Ester, (5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenyl-morpholin-2-one, (5S,6R)-5,6-Diphenyl-4-tert-butoxycarbonylmorpholin-2-one, tert-Butyl (2R,3S)-()-6-oxo-2,3-diphenyl-4-morpholinecarboxylate, (5S,6R)-N-Boc-5,6-diphenyl-2-morpholinone, (2R,3S)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate, tert-butyl (2S,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate, tert-butyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate

Beschreibung

Applications (2R,3S)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid tert-Butyl Ester is a reactant used in the preparation of (-)-Jorumycin, (-)-Renieramycin G, 3-epi-Jorumycin, and 3-epi-Renieramycin G and collagen cross-link pyridinolines.
References Allevi, P. et al.: J. Org. Chem., 72, 3478 (2007); Lane, J. et al.; J. Am. Chem. Soc., 127, 12684 (2005); Allevi, P. & Anastasia, M.: Tetrahderon: Asymm., 15, 2091 (2004)

• Marke: TRC

Chemische Eigenschaften

• Molekulargewicht: 353.41
• Formel: C₂₁H₂₃NO₄
• Farbe/Form: Neat
• InChl: InChI=1S/C21H23NO4/c1-21(2,3)26-20(24)22-14-17(23)25-19(16-12-8-5-9-13-16)18(22)15-10-6-4-7-11-15/h4-13,18-19H,14H2,1-3H3/t18-,19+/m0/s1
• InChI Key: InChIKey=MRUKRSQUUNYOFK-RBUKOAKNSA-N
• SMILES: CC(C)(C)OC(=O)N1CC(=O)O[C@H](c2ccccc2)[C@@H]1c1ccccc1