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CAS 12354-84-6
:Iridio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di-
Descripción:
Iridio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di- es un compuesto organometálico complejo que presenta iridio como el átomo central de metal. Este compuesto se caracteriza por su coordinación con múltiples ligandos, específicamente cloruros y derivados de ciclopentadienilo, que contribuyen a sus propiedades estructurales y electrónicas únicas. La presencia de los sustituyentes pentametilo en los anillos de ciclopentadienilo mejora la estabilidad y solubilidad del complejo. Los complejos de iridio son conocidos por sus propiedades catalíticas, particularmente en la síntesis orgánica y en el campo de la ciencia de materiales. El puente di-μ-cloro indica que los cloruros están actuando como ligandos puentes entre los centros de iridio, lo que puede influir en la reactividad y el entorno de coordinación del metal. En general, este compuesto ejemplifica la intrincada interacción de metal-ligando que define el comportamiento de los complejos de metales de transición en diversas aplicaciones químicas.
Fórmula:C20H30Cl4Ir2
InChI:InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4
Clave InChI:InChIKey=MMAGMBCAIFVRGJ-UHFFFAOYSA-J
SMILES:[Cl-][Ir+3]12345(C=6(C)C1(C)=C2(C)[C-]3(C)C46C)[Cl-][Ir+3]789%10([Cl-])([Cl-]5)[C-]%11(C)C7(C)=C8(C)C9(C)=C%10%11C
Sinónimos:- (Ir(Cp*)Cl<sub>2</sub>)<sub>2</sub>
- (Pentamethylcyclopentadienyl)iridium dichloride dimer
- (Pentamethylcyclopentadienyl)iridium(III)Dichloride Dimer
- (η<sup>5</sup>-Pentamethylcyclopentadienyl)iridium dichloride dimer
- 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, iridium complex
- Bis((μ-chloro)chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(chloro(μ<sub>2</sub>-chloro)(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(dichloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(dichloro(η<sup>5</sup>-η-pentamethylcyclopentadienyl)iridium)
- Bis(pentamethylcyclopentadiene)tetrachlorodiiridium
- Bis(pentamethylcyclopentadienyliridium dichloride)
- Bis(μ-chloro)bis[chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium]
- Bis[dichloro(pentamethylcyclopentadienyl)iridium]
- Di-μ-chlorobis(chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)diiridium
- Dichloro(pentamethylcyclopentadienyl)iridium dimer
- Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
- Dichlorobis(μ<sub>2</sub>-chloro)bis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
- Dichlorodi-μ-chlorobis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
- Dichloropentamethylcyclopentadienyliridiumdimer
- Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
- Pentamethylcyclopentadienyl)iridium(III) chloride dimer
- Pentamethylcyclopentadienyliridium(III) chloride,dimer
- Pentamethylcyclopentadienyliridium(III) dichloride dimer
- Tetrachlorobis(pentamethylcyclopentadienyl)diiridium
- Tetrachlorobis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
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Encontrado 10 productos.
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
CAS:Fórmula:C20H30Cl4Ir2Pureza:>95.0%(T)Forma y color:Light yellow to Brown powder to crystalPeso molecular:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some
Fórmula:C20H30Cl4Ir2Forma y color:Orange, Crystals or crystalline powderPeso molecular:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
Fórmula:(CH3)5C5IrCl2Pureza:98%Forma y color:orange xtl.Peso molecular:796.67Iridium,di-m-chlorodichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
CAS:Fórmula:C20H30Cl4Ir2Pureza:98%Forma y color:SolidPeso molecular:796.6982(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer
CAS:(Pentamethylcyclopentadienyl)iridium(III) dichloride dimerFórmula:C20H30Cl4Ir2Pureza:98%,Ir:48%,high pureForma y color: orange powderPeso molecular:796.70g/molPentamethylcyclopentadienyliridium(III) chloride, dimer
CAS:Fórmula:C20H30Cl4Ir2Pureza:≥ 97.0%Forma y color:Yellow to orange powderPeso molecular:796.70Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Producto controladoApplications Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is commonly found to be used as a catalyst in reactions, and the synthesis oxidative arylation with indoles, azobenzene derivatives., and ortho-alkynylated arylalkylamines.
References Li, G., et al.: Org. Lett., 20, 2454-58 (2018); Tindall, D.J., et al.: J. Am. Chem. Soc., 140, 1884-93 (2018); Chen, X., et al.: Org. Lett., 20, 1171-74 (2018);Fórmula:C20H30Cl4Ir2Forma y color:NeatPeso molecular:796.7DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) DIMER
CAS:Fórmula:C20H30Cl4Ir2Pureza:98%Peso molecular:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer (DCPI) is a synthetic ligand that can be used in biomolecular and chemical applications. DCPI has been shown to be stable in the presence of chloride, which is needed for many catalytic reactions. This compound has high activity as a transfer agent and is also able to transfer amines and cyclic compounds. DCPI can be used in fluorescence-based assays, due to its strong fluorescence emission.Fórmula:C20H30Cl4Ir2Pureza:Min. 95%Forma y color:PowderPeso molecular:796.7 g/mol
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