CAS 138124-32-0

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTILSALICILIDENO)-1,2-CICLOHEXANODIAMINO-MANGANESO(III) CLORURO

Descripción:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTILSALICILIDENO)-1,2-CICLOHEXANODIAMINO-MANGANESO(III) CLORURO es un compuesto de coordinación que presenta un centro de manganeso coordinado a un ligando bidentado derivado de una diamina quiral y derivados de salicilaldehído. Este compuesto se caracteriza por su significativa hindrance estérica debido a la presencia de grupos tert-butilo voluminosos en las moieties salicilideno, que pueden influir en su reactividad y selectividad en procesos catalíticos. El estado de oxidación de manganeso(III) es notable por su capacidad para participar en reacciones redox, lo que hace que este compuesto sea de interés en catálisis y ciencia de materiales. La quiralidad del ligando confiere potencial enantioselectividad en reacciones, lo cual es valioso en síntesis asimétrica. Además, el ion cloruro actúa como un contraión, estabilizando el complejo. Sus características estructurales y propiedades únicas lo convierten en un objeto de estudio en química de coordinación y sus aplicaciones en catálisis, particularmente en transformaciones orgánicas.

Fórmula: C₃₆H₅₂ClMnN₂O₂

InChI: InChI=1/C36H54N2O2.3ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;;;/h17-22,29-30,39-40H,13-16H2,1-12H3;3*1H;/q;;;;+3/p-3/b37-21+,38-22+;;;;/t29-,30-;;;;/m0..../s1

Clave InChI: InChIKey=LJVAWOSDJSQANR-SEILFYAJSA-K

SMILES: [Cl-][Mn+3]123[N]([C@]4([C@]([N]1=CC=5C([O-]2)=C(C(C)(C)C)C=C(C(C)(C)C)C5)(CCCC4)[H])[H])=CC=6C([O-]3)=C(C(C)(C)C)C=C(C(C)(C)C)C6

Sinónimos:

• (+)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-Hexanediamino-Mn Cl
• (-)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-
• (-)-Chloro{(1R,2R)-4,4′,6,6′-tetra-tert-butyl-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III)
• (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]MANGANESE(III)CHLORIDE
• (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]manganese (III) chloride
• (R,R)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexylmanganese(III) chloride
• (R,R)-(-)-N,N'-BIS(3.5-DI-T-Butylsalicylidene)-1,2-CYCLOHEXANEDIAMINE-manganese (III) chloride
• (R,R)-(-)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino manganese(II) chloride
• (R,R)-Jacobsen Cat.
• (R,R)-Jacobsen Catalyst
• (R,R)-Jacobsen'S Catalyst
• (R,R)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (R,R)-[N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-MANGANESE(III) CHLORIDE
• (S,S)-Jacobsen Cat.
• (S,S)-Jacobsen Catalyst
• (S,S)-Jacobsen'S Catalyst
• (S,S)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL-IDENE)-1,2-Cyclohexanediamino-MN-CL
• (SP-5-13)-Chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• 2,2'-{(1S,2S)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• Jacobsen'S Catalyst
• Manganese, chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-5-13)-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-5-13-(1R-trans)]-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, [SP-5-13-(1R-trans)]-
• chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• -N,N'-Bis(3,5-di-tertbutylsalicylidene)
• (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
• (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminemanganese(III)chloride
• (R,R)-(-)-[N,N(1)-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaMinoat(2-)]Manganese(III) chloride
• (R,R)Jacobesn
• (R,R)(-)N,N'Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco
• (R,R)-Jacobsen’s catalyst, Jacobsen’s catalyst
• (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(R,R)-JacobsenCat.
• Jacobsen
• Jacobsen'scatalyst(R,R)
• 96+%(chn)
• (R,R)-form
• (1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese (III) chloride (R,R)-Jacobsen Cat.
• -1,2- cyclohexanediaminomanganese(III)
• (R,R)-N,N -BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL
• (R,R)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL98%

(1R,2R)-(-)-[1,2-Cyclo­hexanediamino-N,N'-bis(3,5-di-t-butyl­salicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

CAS: 138124-32-0

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: 98%

Forma y color: brown pwdr.

Peso molecular: 635.22

Ref: 08-25-0300

(R,R)-Jacobsen's catalyst

CAS: 138124-32-0

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: 97%

Forma y color: Solid

Peso molecular: 635.2013

Ref: IN-DA003CCA

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

Pureza: 98%,99%ee

Peso molecular: 635.21g/mol

Ref: 54-OR72454

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: >98.0%(HPLC)

Forma y color: Orange to Brown powder to crystal

Peso molecular: 635.21

Ref: 3B-B5613

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a diamine ligand that has been used for the immobilization of ethylene. The reaction proceeds via an oxidation catalyzed by a metal such as copper or manganese. The reaction products are chlorides and alcohols. The molecular modeling and x-ray crystal structures of these reactions have been studied and kinetic data have been collected. Kinetics measurements show that the reactions are fast with an activation energy of 45 kcal/mol and proceed through a hydrogen transfer mechanism.

Fórmula: C₃₆H₅₂ClMnN₂O₂

Pureza: Min. 95%

Forma y color: Powder

Peso molecular: 635.2 g/mol

Ref: 3D-FB30906

(R,R)-(-)-N,N’-Bis(3,5-di-tertbutylsalicylidene)-1,2- cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

Pureza: 97%

Peso molecular: 634.31

Ref: 10-F552090