CAS 14694-95-2
:Cloruro de tris(trifenilfosfina)rodio(I)
Descripción:
Cloruro de tris(trifenilfosfina)rodio(I), comúnmente conocido como Rh(PPh₃)₃Cl, es un complejo de coordinación que presenta rodio en un estado de oxidación +1. Este compuesto se caracteriza por su coordinación de tres ligandos de trifenyfosfina (PPh₃) a un átomo central de rodio, junto con un ion cloruro. Típicamente aparece como un sólido de color rojo oscuro a púrpura y es soluble en disolventes orgánicos como el diclorometano y el tolueno. La presencia de los voluminosos ligandos de trifenyfosfina imparte una significativa hindrance estérica, influyendo en la reactividad y estabilidad del complejo. Rh(PPh₃)₃Cl es conocido por sus propiedades catalíticas, particularmente en síntesis orgánica y reacciones de hidrogenación, donde facilita la transferencia de hidrógeno a sustratos insaturados. Además, exhibe propiedades fotofísicas interesantes, lo que lo convierte en un objeto de estudio en química de coordinación y catálisis. Su síntesis a menudo implica la reacción de sales de rodio con trifenyfosfina en presencia de una fuente de cloruro.
Fórmula:C54H45ClP3Rh
InChI:InChI=1/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1/r3C18H15P.ClRh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2/h3*1-15H;
Clave InChI:InChIKey=IXAYKDDZKIZSPV-UHFFFAOYSA-M
SMILES:[Rh+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)([P](C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)[Cl-]
Sinónimos:- (SP-4-2)-Chlorotris(triphenylphosphine)rhodium
- Chlororhodium, Triphenylphosphane
- Chlorotris(Triphenylphosphine)Rhodate (I)
- Chlorotris(Triphenylphosphine)Rhodium
- Chlorotris(Triphenylphosphine)Rhodium(I)
- Decarbon
- Nsc 124140
- Phosphine, Triphenyl-, Chloride, Rhodium Salt (3:1)
- Rhodium Tris(Triphenyl-Phosphine)Chloride
- Rhodium tris(triphenylphosphine) chloride
- Rhodium(I) Tris(Triphenylphosphine) Chloride
- Rhodium(I) Tris(Triphenylphosphine) Chloride Polymer Supported, Wilkinsons Catalyst Polymer Supported
- Rhodium, chlorotris(triphenylphosphine)-
- Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-
- Tris(Tripehnylphosphine)Rhodium(I)Chloride
- Tris(Triphenylphosphine)Rhodium(1) Chloride
- Tris(Triphenylphosphine)Rhodium(I) Chloride Polymer Bound
- Tris(triphenylphosphin)rhodium(I)chlorid
- Tris(triphenylphosphine)chlororhodium
- Tris(triphenylphosphine)chlororhodium(I)
- Tris(triphenylphosphine)rhodium chloride
- Tris(triphenylphosphine)rhodium monochloride
- Wilkinson Catalyst
- Wilkinson's catalyst
- Wilkinson's complex
- Wilkinsons catalyst
- [Tristriphenylphosphine)Rhodium(I) Chloride]
- chlorure de tris(triphenylphosphine)rhodium (I)
- cloruro de tris(trifenilfosfina)rodio (I)
- tris(triphenylphosphine)rhodium i chloride
- Tris(triphenylphosphine)rhodiumchloride
- Tris(triphenylphosphino)chlororhodium
- Chlorotri (triphenylphosphine) rhodium
- Ver más sinónimos
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Encontrado 9 productos.
Tris(triphenylphosphine)rhodium(I) Chloride
CAS:Fórmula:C54H45ClP3RhPureza:>98.0%(T)Forma y color:Orange to Brown to Dark red powder to crystalPeso molecular:925.23Chlorotris(triphenylphosphine)rhodium(I), 97%
CAS:Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information
Fórmula:C54H45ClP3RhPureza:97%Peso molecular:925.23Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST
CAS:Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST
Fórmula:RhCl(P(C6H5)3Pureza:99%Forma y color:maroon xtl.Peso molecular:925.23Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-
CAS:Fórmula:C54H45ClP3RhPureza:98%Forma y color:SolidPeso molecular:925.2149Tris(triphenylphosphine)rhodium(I) chloride
CAS:Tris(triphenylphosphine)rhodium(I) chloridePureza:98%,Rh:11%,high pureForma y color:SolidPeso molecular:925.21g/molTris(triphenylphosphine)rhodium(I) chloride, 99.95% (metals basis)
CAS:Fórmula:(C6H5)3PRhClPeso molecular:925.23Tris(triphenylphosphine)rhodium(I) Chloride
CAS:Producto controladoApplications Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodium(I) Chloride is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
References Evans, D.A. et al.: J. Am. Chem. Soc., 110, 6917 (1988); Ojima, I. et al.: Tetrahedron Lett., 13, 5035 (1972); Birch, A.J. et al.: Org. React., 24 (1976);Fórmula:C54H45ClP3RhForma y color:NeatPeso molecular:925.21Chlorotris(triphenylphosphine)rhodium(I)
CAS:Fórmula:C54H45ClP3RhPureza:97%Forma y color:SolidPeso molecular:925.23Tris(triphenylphosphine)rhodium(I) chloride
CAS:Homogeneous hydrogenation catalyst
Fórmula:C54H45ClP3RhPureza:Min. 95%Forma y color:PowderPeso molecular:925.21 g/mol
