CAS 14694-95-2

Cloruro de tris(trifenilfosfina)rodio(I)

Descripción:

Cloruro de tris(trifenilfosfina)rodio(I), comúnmente conocido como Rh(PPh₃)₃Cl, es un complejo de coordinación que presenta rodio en un estado de oxidación +1. Este compuesto se caracteriza por su coordinación de tres ligandos de trifenyfosfina (PPh₃) a un átomo central de rodio, junto con un ion cloruro. Típicamente aparece como un sólido de color rojo oscuro a púrpura y es soluble en disolventes orgánicos como el diclorometano y el tolueno. La presencia de los voluminosos ligandos de trifenyfosfina imparte una significativa hindrance estérica, influyendo en la reactividad y estabilidad del complejo. Rh(PPh₃)₃Cl es conocido por sus propiedades catalíticas, particularmente en síntesis orgánica y reacciones de hidrogenación, donde facilita la transferencia de hidrógeno a sustratos insaturados. Además, exhibe propiedades fotofísicas interesantes, lo que lo convierte en un objeto de estudio en química de coordinación y catálisis. Su síntesis a menudo implica la reacción de sales de rodio con trifenyfosfina en presencia de una fuente de cloruro.

Fórmula: C₅₄H₄₅ClP₃Rh

InChI: InChI=1/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1/r3C18H15P.ClRh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2/h3*1-15H;

Clave InChI: InChIKey=IXAYKDDZKIZSPV-UHFFFAOYSA-M

SMILES: [Rh+]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)([P](C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)[Cl-]

Sinónimos:

• (SP-4-2)-Chlorotris(triphenylphosphine)rhodium
• Chlororhodium, Triphenylphosphane
• Chlorotris(Triphenylphosphine)Rhodate (I)
• Chlorotris(Triphenylphosphine)Rhodium
• Chlorotris(Triphenylphosphine)Rhodium(I)
• Decarbon
• Nsc 124140
• Phosphine, Triphenyl-, Chloride, Rhodium Salt (3:1)
• Rhodium Tris(Triphenyl-Phosphine)Chloride
• Rhodium tris(triphenylphosphine) chloride
• Rhodium(I) Tris(Triphenylphosphine) Chloride
• Rhodium(I) Tris(Triphenylphosphine) Chloride Polymer Supported, Wilkinsons Catalyst Polymer Supported
• Rhodium, chlorotris(triphenylphosphine)-
• Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-
• Tris(Tripehnylphosphine)Rhodium(I)Chloride
• Tris(Triphenylphosphine)Rhodium(1) Chloride
• Tris(Triphenylphosphine)Rhodium(I) Chloride Polymer Bound
• Tris(triphenylphosphin)rhodium(I)chlorid
• Tris(triphenylphosphine)chlororhodium
• Tris(triphenylphosphine)chlororhodium(I)
• Tris(triphenylphosphine)rhodium chloride
• Tris(triphenylphosphine)rhodium monochloride
• Wilkinson Catalyst
• Wilkinson's catalyst
• Wilkinson's complex
• Wilkinsons catalyst
• [Tristriphenylphosphine)Rhodium(I) Chloride]
• chlorure de tris(triphenylphosphine)rhodium (I)
• cloruro de tris(trifenilfosfina)rodio (I)
• tris(triphenylphosphine)rhodium i chloride
• Tris(triphenylphosphine)rhodiumchloride
• Tris(triphenylphosphino)chlororhodium
• Chlorotri (triphenylphosphine) rhodium

Tris(triphenylphosphine)rhodium(I) Chloride

CAS: 14694-95-2

Fórmula: C₅₄H₄₅ClP₃Rh

Pureza: >98.0%(T)

Forma y color: Orange to Brown to Dark red powder to crystal

Peso molecular: 925.23

Ref: 3B-T0931

Chlorotris(triphenylphosphine)rhodium(I), 97%

CAS: 14694-95-2

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information

Fórmula: C₅₄H₄₅ClP₃Rh

Pureza: 97%

Peso molecular: 925.23

Ref: 02-010468

Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST

CAS: 14694-95-2

Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST

Fórmula: RhCl(P(C₆H₅)₃

Pureza: 99%

Forma y color: maroon xtl.

Peso molecular: 925.23

Ref: 08-45-0650

Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-

CAS: 14694-95-2

Fórmula: C₅₄H₄₅ClP₃Rh

Pureza: 98%

Forma y color: Solid

Peso molecular: 925.2149

Ref: IN-DA001EH1

Tris(triphenylphosphine)rhodium(I) chloride

CAS: 14694-95-2

Tris(triphenylphosphine)rhodium(I) chloride

Pureza: 98%,Rh:11%,high pure

Forma y color: Solid

Peso molecular: 925.21g/mol

Ref: 54-IN3720

Tris(triphenylphosphine)rhodium(I) chloride, 99.95% (metals basis)

CAS: 14694-95-2

Fórmula: (C₆H₅)₃PRhCl

Peso molecular: 925.23

Ref: 7W-GX2604

Tris(triphenylphosphine)rhodium(I) Chloride

Producto controlado

CAS: 14694-95-2

Applications Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodium(I) Chloride is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
References Evans, D.A. et al.: J. Am. Chem. Soc., 110, 6917 (1988); Ojima, I. et al.: Tetrahedron Lett., 13, 5035 (1972); Birch, A.J. et al.: Org. React., 24 (1976);

Fórmula: C₅₄H₄₅ClP₃Rh

Forma y color: Neat

Peso molecular: 925.21

Ref: TR-T886465

Tris(triphenylphosphine)rhodium(I) chloride

CAS: 14694-95-2

Homogeneous hydrogenation catalyst

Fórmula: C₅₄H₄₅ClP₃Rh

Pureza: Min. 95%

Forma y color: Powder

Peso molecular: 925.21 g/mol

Ref: 3D-FT29106

Chlorotris(triphenylphosphine)rhodium(I)

CAS: 14694-95-2

Fórmula: C₅₄H₄₅ClP₃Rh

Pureza: 97%

Forma y color: Solid

Peso molecular: 925.23

Ref: 10-F048596