CAS 17567-17-8

Hidruro de potasio tris(3,5-dimetilpirazolil)borato

Descripción:

Hidruro de potasio tris(3,5-dimetilpirazolil)borato, comúnmente conocido como K[HB(3,5-DMP)3], es un compuesto de coordinación que presenta un centro de boro coordinado a tres ligandos de 3,5-dimetilpirazol. Este compuesto se caracteriza por su estructura única, donde el átomo de boro está estabilizado por la presencia de los anillos de pirazol, que contribuyen a sus propiedades quelantes. El ion potasio actúa como contraión, equilibrando la carga negativa del complejo de borato. Esta sustancia es conocida por su papel en diversas reacciones químicas, particularmente en el campo de la química organometálica y la catálisis, donde puede actuar como un ligando para metales de transición. Exhibe buena solubilidad en disolventes polares y es relativamente estable en condiciones de laboratorio estándar. La presencia de los grupos dimetilo en los anillos de pirazol aumenta el volumen estérico alrededor del centro de boro, influyendo en su reactividad e interacción con otras especies químicas. En general, Hidruro de potasio tris(3,5-dimetilpirazolil)borato es un compuesto valioso en la química sintética, particularmente en el desarrollo de nuevos sistemas catalíticos.

Fórmula: C₁₅H₂₂BKN₆

InChI: InChI=1/C15H22BN6.K/c1-10-7-13(4)20(17-10)16(21-14(5)8-11(2)18-21)22-15(6)9-12(3)19-22;/h7-9,16H,1-6H3;/q-1;+1

Clave InChI: InChIKey=NTWZGFNSHCFHIJ-UHFFFAOYSA-N

SMILES: [B+3]([H-])([N-]1C(C)=CC(C)=N1)([N-]2C(C)=CC(C)=N2)[N-]3C(C)=CC(C)=N3.[K+]

Sinónimos:

• 1H-Pyrazole, 3,5-dimethyl-, boron complex
• Borate(1-), tris(3,5-dimethyl-1H-pyrazolato-N¹)hydro-, potassium, (T-4)-
• Borate(1-), tris(3,5-dimethyl-1H-pyrazolato-κN¹)hydro-, potassium, (T-4)-
• Borate(1-), tris(3,5-dimethylpyrazolato)hydro-, potassium
• NSC 376448
• Potassium Tris(3,5-Dimethyl-1-Pyrazolyl)-Borohydride
• Potassium Tris(3,5-Dimethylpyrazol-1-Yl)Borohydride
• Potassium hydridotris(3,5-dimethylpyrazol-1-yl)borate
• Potassium hydridotris(3,5-dimethylpyrazolyl)borate(1-)
• Potassium hydridotris-(3,5-dimethylpyrazolyl)borate
• Potassium hydrotris(3,5-dimethyl-1H-pyrazol-1-yl)borate
• Potassium hydrotris(3,5-dimethyl-1H-pyrazol-1-yl)borate(1-)
• Potassium hydrotris(3,5-dimethylpyrazol-1-yl)borate(1-)
• Potassium hydrotris(3,5-dimethylpyrazolyl)borate
• Potassium hydrotris(3,5-dimethylpyrazolyl)borate(1-)
• Potassium tri(3,5-dimethyl-1-pyrazolyl)borohydride
• Potassium tris(3,5-dimethylpyrazol-1-yl)hydroborate
• Potassium tris(3,5-dimethylpyrazolyl)hydroborate
• Potassiumhydrotris(3,5-dimethylpyrazol-1-yl)borate,97%
• potassium tris(3,5-dimethyl-1H-pyrazol-1-yl)(hydrido)borate(1-)
• Borate(1-), tris(3,5-dimethyl-1H-pyrazolato-N1)hydro-, potassium, (T-4)-
• Borate(1-), tris(3,5-dimethyl-1H-pyrazolato-κN1)hydro-, potassium, (T-4)-
• Scorpionates
• Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride,99%
• POTASSIUM HYDROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE
• Tp ligand

Potassium Tris(3,5-dimethylpyrazol-1-yl)borohydride

CAS: 17567-17-8

Fórmula: C₁₅H₂₂BKN₆

Pureza: >98.0%(T)

Forma y color: White to Almost white powder to crystal

Peso molecular: 336.29

Ref: 3B-P1441

Potassium hydrotris(3,5-dimethylpyrazol-1-yl)borate, 97%

CAS: 17567-17-8

Potassium hydrotris(3,5-dimethylpyrazol-1-yl)borate, 97%

Fórmula: C₁₅H₂₂BN₆K

Pureza: 97%

Forma y color: white pwdr.

Peso molecular: 336.29

Ref: 08-19-2900

POTASSIUM HYDROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE

CAS: 17567-17-8

Fórmula: C₁₅H₂₂BKN₆

Pureza: 98%

Forma y color: Solid

Peso molecular: 336.2847

Ref: IN-DA003TWM

Potassiumhydrotris(3,5-Dimethylpyrazol-1-Yl)Borate

CAS: 17567-17-8

Potassiumhydrotris(3,5-Dimethylpyrazol-1-Yl)Borate

Pureza: 98%

Peso molecular: 336.28g/mol

Ref: 54-OR1027146

Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride

CAS: 17567-17-8

Pureza: 98.0%

Forma y color: Solid

Peso molecular: 336.29

Ref: 10-F075306

Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride

CAS: 17567-17-8

Potassium tris(3,5-dimethyl-1-pyrazolyl)borohydride is a catalytic reagent that converts various ketones to their corresponding cyclic 3,5-dimethylpyrazoles. It has been used for the synthesis of 1,4-dihydropyridines and for the conversion of aliphatic nitro compounds to their corresponding anilines. The yields are high and it has been shown to be more efficient than other methods in the literature. This reagent also has an intramolecular reaction mechanism and is able to reduce chloride ions into chloride gas.

Fórmula: C₁₅H₂₂BKN₆

Pureza: Min. 95%

Forma y color: Powder

Peso molecular: 336.28 g/mol

Ref: 3D-FP63125