CAS 27607-77-8

Trifluorometilsilil trifluorometanosulfonato

Descripción:

Trifluorometilsilil trifluorometanosulfonato, con el número CAS 27607-77-8, es un compuesto químico que sirve como un potente agente silylante y un reactivo en la síntesis orgánica. Se caracteriza por su grupo trifluorometano, que mejora su reactividad, haciéndolo útil en varias transformaciones químicas, particularmente en la protección de alcoholes y aminas. El compuesto es típicamente un líquido incoloro a amarillo pálido con un olor penetrante y es conocido por su alta volatilidad. Trifluorometilsilil trifluorometanosulfonato es soluble en disolventes orgánicos como el diclorometano y el acetonitrilo, pero es menos soluble en agua. Es altamente reactivo y puede hidrolizarse en presencia de humedad, liberando ácido trifluoroacético, que es un ácido fuerte. Debido a su reactividad, debe manejarse con cuidado, utilizando medidas de seguridad apropiadas para evitar el contacto con la piel y los ojos, así como la inhalación de vapores. Sus aplicaciones se extienden a áreas como la química de polímeros, donde puede facilitar la síntesis de moléculas y materiales complejos.

Fórmula: C₄H₉F₃O₃SSi

InChI: InChI=1/C18H3F35O6/c19-2(1-54,8(26,27)28)55-15(46,47)4(22,10(32,33)34)57-17(50,51)6(24,12(38,39)40)59-18(52,53)7(25,13(41,42)43)58-16(48,49)5(23,11(35,36)37)56-14(44,45)3(20,21)9(29,30)31/h54H,1H2

Clave InChI: InChIKey=FTVLMFQEYACZNP-UHFFFAOYSA-N

SMILES: S(O[Si](C)(C)C)(C(F)(F)F)(=O)=O

Sinónimos:

• Methanesulfonate, Trimethylsilyl Trifluoro-
• Methanesulfonic acid, 1,1,1-trifluoro-, trimethylsilyl ester
• Silanol, trimethyl-, trifluoromethanesulfonate
• TMSOTf
• Trifluorometanosulfonato De Trimetilsililo
• Trifluoromethanesulfonate de trimethylsilyle
• Trifluoromethanesulfonic acid trimethylsilyl ester
• Trimethylsilanol trifluoromethanesulfonate
• Trimethylsilyl Trifluoromethanesulphonate
• Trimethylsilyl trfluoromethanesulfonate
• Trimethylsilyl triflate
• Trimethylsilyl trifluoromethanesulfonate
• Trimethylsilyl trifluoromethylsulfonate
• Trimethylsilyltrifluormethansulfonat
• Trimethylsilyl trifluoromethylsulphonate
• Methanesulfonic acid, trifluoro-, trimethylsilyl ester
• Trimethylsilyltrifluoromethanesulfonate
• trimethyl-(trifluoromethylsulfonyloxy)silane
• trifluoro-methanesulfonicacitrimethylsilylester
• Methanesulfonicacid,trifluoro-,trimethylsilylester
• Trimethylsllytrifluoromethanesulphonate
• Trimethylsilyltrifluoromethanesulfonate,Anti-Tumor
• CT3795
• trimethylsilyl-trifluoromethansulfonate
• TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE 99%
• Trifluormethansulfonicanhydrid
• TMS TRIFLATE
• SILANE TMS-TRIFLATE

Trimethylsilyl Trifluoromethanesulfonate

CAS: 27607-77-8

Fórmula: C₄H₉F₃O₃SSi

Pureza: >98.0%(T)

Forma y color: Colorless to Light yellow to Light orange clear liquid

Peso molecular: 222.25

Ref: 3B-T0871

Trimethylsilyl trifluoromethanesulfonate, 99%

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their en

Fórmula: C₄H₉F₃O₃SSi

Pureza: 99%

Forma y color: Clear, colorless to pale yellow or pale pink, Liquid

Peso molecular: 222.25

Ref: 02-A12535

Trimethylsilyl trifluoromethanesulfonate, min. 97%

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulfonate, min. 97%

Fórmula: CF₃SO₃Si(CH₃)₃

Pureza: min. 97%

Forma y color: colorless liq.

Peso molecular: 222.26

Ref: 08-14-8600

Trimethylsilyl trifluoromethanesulphonate

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulphonate

Fórmula: C₄H₉F₃O₃SSi

Pureza: 98%

Forma y color: clear. dark yellow to very dark yellow liquid

Peso molecular: 222.25816g/mol

Ref: 54-PC7867

Trimethylsilyl trifluoromethanesulphonate

CAS: 27607-77-8

S20400 - Trimethylsilyl trifluoromethanesulphonate

Fórmula: C₄H₉F₃O₃SSi

Pureza: 98%

Forma y color: Liquid, Clear

Peso molecular: 222.25

Ref: 10-S20400

Trifluoromethanesulfonic acid trimethylsilyl ester

CAS: 27607-77-8

Used in a Dieckmann-like cyclization of ester-imides and diesters

Fórmula: C₄H₉F₃O₃SSi

Pureza: Titration Min. 98%

Forma y color: Yellow Clear Liquid

Peso molecular: 222.26 g/mol

Ref: 3D-FT03406

TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE CYLINDER

CAS: 27607-77-8

Trimethylsilyl Blocking Agent
Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.
Trimethylsilyltrifluoromethanesulfonate; Trimethylsilyltriflate; TMSOTf
Strong silylating agent for C- or O-silylationsReacts with nitroalkanes to give N,N-bis(trimethylsiloxy)enaminesNafion SAC-13 has been shown to be a recyclable catalyst for the trimethylsilylation of primary, secondary, and tertiary alcohols in excellent yields and short reaction timesSummary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure

Fórmula: C₄H₉F₃O₃SSi

Forma y color: Straw Liquid

Peso molecular: 222.25

Ref: 3H-SIT8620.0

Trimethylsilyl trifluoromethane sulfonate

CAS: 27607-77-8

Trimethylsilyl trifluoromethane sulfonate (TMSOTf) is a versatile building block for the synthesis of complex organic compounds. It is a reagent and an intermediate for the production of other fine chemicals and speciality chemicals. TMSOTf is mainly used as a catalyst in organic reactions, such as the Suzuki-Miyaura reaction. TMSOTf can be used to synthesize pharmaceuticals, agrochemicals, and other important chemical products. This compound has been shown to be useful in the construction of synthetic scaffolds that are found in many drug molecules.

Fórmula: C₄H₉F₃O₃SSi

Peso molecular: 222.26 g/mol

Ref: 3D-T-6700