CAS 2873-29-2

Tri-O-acetil-D-glucal

Descripción:

Tri-O-acetil-D-glucal es un compuesto químico que pertenece a la clase de los carbohidratos, específicamente un derivado de D-glucosa. Se caracteriza por la presencia de tres grupos acetilo unidos a los grupos hidroxilo de la estructura glucal, lo que mejora su estabilidad y solubilidad en disolventes orgánicos. Este compuesto típicamente aparece como un líquido incoloro a amarillo pálido o sólido, dependiendo de su forma y pureza. Tri-O-acetil-D-glucal es conocido por su reactividad, particularmente en reacciones de glicosilación, lo que lo convierte en un intermediario valioso en la síntesis orgánica y la química de carbohidratos. Su estructura incluye un doble enlace entre el carbono anomérico y el carbono adyacente, lo que contribuye a sus propiedades químicas únicas. El compuesto se utiliza a menudo en la síntesis de varios glicosidos y oligosacáridos, y sus grupos acetilo pueden ser eliminados bajo condiciones específicas para obtener D-glucal. Al igual que muchos compuestos acetilados, es importante manejar Tri-O-acetil-D-glucal con cuidado, ya que puede presentar riesgos asociados con la inflamabilidad y la reactividad.

Fórmula: C₁₂H₁₆O₇

InChI: InChI=1S/C12H16O7/c1-7(13)17-6-11-12(19-9(3)15)10(4-5-16-11)18-8(2)14/h4-5,10-12H,6H2,1-3H3/t10-,11-,12+/m1/s1

Clave InChI: InChIKey=LLPWGHLVUPBSLP-UTUOFQBUSA-N

SMILES: O(C(C)=O)[C@H]1[C@H](OC(C)=O)C=CO[C@@H]1COC(C)=O

Sinónimos:

• 1,2-Dideoxy-3,4,6-Tri-O-Acetyl-D-Arabino-1-Hexenopyranoside
• 1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose
• 1,3,4-tri-O-acetyl-2,6-anhydro-5-deoxyhex-5-enitol
• 1,5-Anhydro-2-deoxy-D-arabino-1-hexenol triacetate
• 1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol 3,4,6-Tri-O-acetyl Ether
• 1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate
• 1,5-Anhydro-2-desoxy-D-arabino-hex-1-enitoltriacetat
• 3,4,6-Tri-O-Acetyl-1,5-Anhydro-D-Arabino-Hex-1-Enitol
• 3,4,6-Tri-O-acetyl-1,2-dideoxy-<span class="text-smallcaps">D</span>-arabino-hex-1-enopyranose
• 3,4,6-Tri-O-acetyl-1,2-dideoxy-D-arabino-hex-1-enopyranose
• 3,4,6-Tri-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol
• 3,4,6-Tri-O-acetyl-<span class="text-smallcaps">D</span>-glucal
• 3,4,6-Tri-O-acetyl-D-glucal
• 3,4,6-Tri-O-acetylglucal
• 3,4,6-Triacetylglucal
• 3,4,6-Tris-O-acetyl-<span class="text-smallcaps">D</span>-glucal
• 3,4,6-Tris-O-acetyl-D-glucal
• <span class="text-smallcaps">D</span>-Glucal triacetate
• <span class="text-smallcaps">D</span>-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate
• <span class="text-smallcaps">D</span>-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, triacetate
• <span class="text-smallcaps">D</span>-arabino-Hex-1-enopyranose, 1,2-dideoxy-, triacetate
• D-Glucal triacetate
• D-Glucal-3,4,5-tri-O-acetate
• D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate
• D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, triacetate
• D-arabino-Hex-1-enopyranose, 1,2-dideoxy-, triacetate
• Glucal (D)- Tri-O-Acetyl-, (-)-
• Tri-O-acetyl-<span class="text-smallcaps">D</span>-glucal
• Tri-O-acetylglucal
• Triacetate de 1,5-anhydro-2-desoxy-D-arabino-hex-1-enitol
• Triacetyl-<span class="text-smallcaps">D</span>-glucal
• Triacetyl-D-glucal

Tri-O-acetyl-D-glucal

CAS: 2873-29-2

Fórmula: C₁₂H₁₆O₇

Pureza: >96.0%(GC)

Forma y color: White to Almost white powder to crystal

Peso molecular: 272.25

Ref: 3B-T1596

3,4,6-Tri-O-acetyl-D-glucal, 98%

CAS: 2873-29-2

3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar pro

Fórmula: C₁₂H₁₆O₇

Pureza: 98%

Forma y color: Crystals or powder or crystalline powder, White

Peso molecular: 272.25

Ref: 02-L14103

D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-, 3,4,6-triacetate

CAS: 2873-29-2

Fórmula: C₁₂H₁₆O₇

Pureza: 98%

Forma y color: Solid

Peso molecular: 272.2512

Ref: IN-DA002WA2

Tri-O-acetyl-D-glucal

CAS: 2873-29-2

Fórmula: C₁₂H₁₆O₇

Pureza: (GC) ≥ 98.0%

Forma y color: White to off-white crystalline powder or crystals

Peso molecular: 272.26

Ref: 7W-GC8339

(2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate

CAS: 2873-29-2

Pureza: 95.0%

Forma y color: Solid

Peso molecular: 272.25299072265625

Ref: 10-F235533

Tri-O-acetyl-D-glucal

CAS: 2873-29-2

Forma y color: Neat

Ref: 86-MM3981.07

3,4,6-Tri-O-acetyl-D-glucal

CAS: 2873-29-2

3,4,6-Tri-O-acetyl-D-glucal

Pureza: 98%

Peso molecular: 272.25g/mol

Ref: 54-BISY011

3,4,6-Tri-O-acetyl-D-glucal

CAS: 2873-29-2

3,4,6-Tri-O-acetyl-D-glucal, also called 1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate, is the acetate protected cyclic enol-ether (glycal) of D-glucose. 3,4,6-Tri-O-acetyl-D-glucal is a building block useful in the synthesis of a range of carbohydrates with the glucal double bond allowing other functional groups to be introduced. As an alkene, a glycal can undergo electrophilic addition across the double bond to introduce halogens and epoxides or be used to generate deoxy monosaccharides. 3,4,6-Tri-O-acetyl-D-glucal can undergo a Ferrier rearrangement with an alcohol and Lewis acid to give a 2,3-unsaturated product.

Fórmula: C₁₂H₁₆O₇

Pureza: Min. 98 Area-%

Forma y color: White Off-White Powder

Peso molecular: 272.25 g/mol

Ref: 3D-MT00681

Tri-O-acetyl-D-glucal

Producto controlado

CAS: 2873-29-2

Applications A D-glucal derivative.

Fórmula: C₁₂H₁₆O₇

Forma y color: Neat

Peso molecular: 272.2512

Ref: TR-T764800