CAS 301224-40-8

(SP-5-41)-[1,3-Bis(2,4,6-trimetilfenil)-2-imidazolidinilideno]dicloruro[[2-(1-metiletoxil-κO)fenil]metileno-κC]rutenio

Descripción:

La sustancia química conocida como (SP-5-41)-[1,3-Bis(2,4,6-trimetilfenil)-2-imidazolidinilideno]dicloruro[[2-(1-metiletoxil-κO)fenil]metileno-κC]rutenio, con el número CAS 301224-40-8, es un complejo organometálico que presenta un centro de rutenio coordinado a varios ligandos. Este compuesto se caracteriza por su ligando imidazolidinilideno, que es un tipo de carbeno N-heterocíclico (NHC) conocido por su fuerte capacidad de donación σ, lo que mejora la estabilidad y reactividad del centro metálico. La presencia de grupos dicloruro indica que tiene dos ligandos de cloruro, lo que puede influir en su reactividad y propiedades de coordinación. El compuesto también contiene un grupo fenilo con un sustituyente éter, que puede afectar su solubilidad e interacción con otras moléculas. Tales complejos de rutenio se estudian a menudo por sus propiedades catalíticas en síntesis orgánica, particularmente en reacciones de acilo cruzado y procesos de metátasis. En general, este compuesto ejemplifica el diseño intrincado de marcos organometálicos que son fundamentales en la química sintética moderna.

Fórmula: C₃₁H₃₈Cl₂N₂ORu

InChI: InChI=1/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2/rC31H38Cl2N2ORu/c1-20(2)36-28-12-10-9-11-27(28)19-37(32,33)31-34(29-23(5)15-21(3)16-24(29)6)13-14-35(31)30-25(7)17-22(4)18-26(30)8/h9-12,15-20H,13-14H2,1-8H3

Clave InChI: InChIKey=LNZKORSBJYPKDX-UHFFFAOYSA-L

SMILES: [Cl-][Ru+6]=1([Cl-])(O(C(C)C)C=2C([CH-2]1)=CC=CC2)=[C-2]3N(CCN3C4=C(C)C=C(C)C=C4C)C5=C(C)C=C(C)C=C5C

Sinónimos:

• (1,3-Bis-(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene)Dichloro(O-Isopropoxyphenylmethylene)Ruthenium
• (1,3-Dimesityl-2-imidazolidinylidene)(o-isopropoxyphenylmethylene)ruthenium dichloride
• (SP-5-41)-[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]ruthenium
• C 627
• Grubbs 2nd catalyst
• Grubbs-Hoveyda 2nd generation catalyst
• Grubbs-Hoveyda catalyst
• Hoveyda II catalyst
• Hoveyda catalyst
• Hoveyda grubbs II catalyst
• Hoveyda second generation catalyst
• Hoveyda-Grubbs 2nd generation catalyst
• Hoveyda-Grubbs Catalyst 2nd
• Hoveyda-Grubbs catalyst
• Hoveyda-Grubbs second generation catalyst
• Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]-, (SP-5-41)-
• Second generation Hoveyda Grubbs catalyst
• Second-generation Hoveyda catalyst
• [1,3-Bis(2,4,6-Trimethylphenyl)Imidazolidin-2-Ylidene](Dichloro){[2-(1-Methylethoxy)Phenyl]Methylidene}Ruthenium
• [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]ruthenium
• Hoveyda-Grubbs II
• (1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM
• Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM
• Hoveyda-Grubbs Catalyst 2nd Generation,97%
• HOVEYDA-GRUBBS
• 301224-40-8
• Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium
• Hoveyda-Grubbs Catalyst 2nd Generation 97%
• RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE]
• (1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride
• Hoveyda-Grubbs 2nd
• [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium

Hoveyda-Grubbs Catalyst 2nd Generation

CAS: 301224-40-8

Fórmula: C₃₁H₃₈Cl₂N₂ORu

Pureza: 98%

Forma y color: Solid

Peso molecular: 626.6222

Ref: IN-DA003504

(1,3-Bis-(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene)Dichloro(Oisopropoxyphenylmethylene)Ruthenium

CAS: 301224-40-8

(1,3-Bis-(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene)Dichloro(Oisopropoxyphenylmethylene)Ruthenium

Pureza: 98%+

Peso molecular: 626.62g/mol

Ref: 54-OR1007793

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium

CAS: 301224-40-8

Applications [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium is a cross-metathesis catalyst used for installation of S-allylcysteine in proteins for enabling olefin metathesis on proteins.
References Lin, Y.A., et al.: J. Am. Chem. Soc., 132, 16805 (2010); Chalker, J.M., et al.: Chem. Comm., no vol., 3714 (2009)

Fórmula: C₃₁H₃₈Cl₂N₂ORu

Forma y color: Neat

Peso molecular: 626.62

Ref: TR-B588655