CAS 887919-35-9

Diclorobis[di-terc-butil(4-dimetilaminofenil)fosfino]paladio(II)

Descripción:

Diclorobis[di-terc-butil(4-dimetilaminofenil)fosfino]paladio(II) es un complejo de paladio caracterizado por su coordinación de paladio con dos ligandos de fosfina bidentados. La estructura presenta un centro de paladio coordinado a dos iones de cloruro y dos ligandos de fosfina voluminosos, que se derivan de la di-terc-butil(4-dimetilaminofenil)fosfina. Este complejo es notable por sus posibles aplicaciones en catálisis, particularmente en reacciones de acilo cruzado, debido a las favorables propiedades electrónicas y estéricas impartidas por los ligandos de fosfina. La presencia del grupo dimetilamino mejora la capacidad de donación de electrones de los ligandos, lo que puede influir en la reactividad del centro de paladio. Además, los voluminosos grupos terc-butil proporcionan impedimento estérico, lo que puede ayudar a estabilizar el complejo y prevenir reacciones secundarias no deseadas. En general, este compuesto ejemplifica la versatilidad de los complejos de paladio en la síntesis orgánica y la ciencia de materiales, mostrando la interacción entre el diseño de ligandos y la actividad catalítica.

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

InChI: InChI=1/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2

SMILES: CC(C)(C)P(c1ccc(cc1)N(C)C)C(C)(C)C.CC(C)(C)P(c1ccc(cc1)N(C)C)C(C)(C)C.Cl.Cl.[Pd]

Sinónimos:

• 4-(Di-tert-butylphosphino)-N,N-dimethylaniline-dichloropalladium (2:1)
• 4-(di-tert-butylphosphanyl)-N,N-dimethylaniline-dichloropalladium (2:1)
• Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
• Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine) palladium(II)
• (A-taPhos)2PdCl2
• (AmPhos)2PdCl2

Bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]dichloropalladium(II)

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: >98.0%(T)

Forma y color: Light yellow to Yellow to Orange powder to crystal

Peso molecular: 708.08

Ref: 3B-B6255

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15%

CAS: 887919-35-9

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides. This Thermo Scientific brand product was originally part of the Alfa Aesar product por

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Peso molecular: 708.08

Ref: 02-045511

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos

CAS: 887919-35-9

Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos

Fórmula: (C₁₆H₂₈NP)₂PdCl₂

Pureza: min. 98%

Forma y color: yellow pwdr.

Peso molecular: 708.07

Ref: 08-46-0825

Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline); palladium chloride

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: 98%

Forma y color: Solid

Peso molecular: 708.0740

Ref: IN-DA0035ZO

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride

CAS: 887919-35-9

Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride

Fórmula: ·2C₁₆H₂₈NP·Cl₂Pd

Pureza: 97%

Forma y color: yellow solid

Peso molecular: 708.07396g/mol

Ref: 54-OR17048

PdCl2(amphos)2 (HPMC encapsulated)

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Forma y color: White to Light yellow capsule

Peso molecular: 708.08

Ref: 3B-R0306

Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline)-palladium chloride

CAS: 887919-35-9

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: 98%

Forma y color: Solid

Peso molecular: 708.08

Ref: 10-F051339

Bis(4-(di-tert-butylphosphino)-N,N-dimethylbenzenamine) palladium dichloride

Producto controlado

CAS: 887919-35-9

Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) is a boronic acid that has been used as a surfactant in organic chemistry. It is hydrophobic and has hydrogen bonding interactions with other molecules. Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) is also a proton acceptor and can form stable complexes with metal ions such as palladium chloride. This compound is kinase selective and can be used to inhibit tyrosine kinases by binding to the ATP binding site of the enzyme's kinase domain. The functional groups of this compound are able to undergo cross-coupling reactions with other functional groups that have been activated by a reagent such as palladium chloride. Bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) has been used in high

Fórmula: C₃₂H₅₆Cl₂N₂P₂Pd

Pureza: Min. 95%

Forma y color: Powder

Peso molecular: 708.07 g/mol

Ref: 3D-FB72418