Methyl coumalate, 98%

CAS: 6018-41-3

Ref. 02-B25330

Información del producto

• Nombre: Methyl coumalate, 98%
• Sinónimos: methyl 6-oxopyran-3-carboxylate, 2H-Pyran-5-carboxylic acid, 2-oxo-, methyl ester, 2H-Pyran-5-carboxylic acid, 2-oxo-, methyl ester (8CI)(9CI), 5-(Carbomethoxy)-2-pyrone, 5-(Methoxycarbonyl)-2-pyrone, Coumalic acid, methyl ester, Cumalic acid methyl ester, Glutaconic acid, 4-(hydroxymethylene)-, δ-lactone, methyl ester, Methyl 2-oxo-2H-pyran-5-carboxylate, Methyl 2-pyrone-5-carboxylate, Methyl cumalate, Nsc 137387, Nsc 34627
• CAS: 6018-41-3

Descripción

Methyl coumalate is a 2-pyrone and acts as dienophile in Diels-Alder reaction. It reacts with 1,3-butadienes at 100°C to yield tetrahydrocoumarins and 4-methoxycarbonyltricyclo[3.2.1.02,7]octenes. It also reacts with cyclohexadiene to afford tetrahydronaphthalene-2-carboxylate. It undergoes Diels-Alder reaction with unactivated alkenes to afford para-substituted adducts. It has been used as reagent in phosphine-catalyzed [4+3] annulation of modified allylic carbonates. It was also used in the preparation of 7-carboxyquinolizinium derivatives. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Marca: Alfa Aesar By Thermo Fisher Scientific

Propiedades químicas

• Peso molecular: 154.12
• Fórmula: C₇H₆O₄
• Pureza: 98%
• Color/Forma: White to cream to pale yellow, Powder
• Clave InChI: HHWWWZQYHPFCBY-UHFFFAOYSA-N