tert-Buty ethyl malonate

CAS: 32864-38-3

Ref. 3D-FB34205

Información del producto

• Nombre: tert-Buty ethyl malonate
• Sinónimos: 1-(1,1-Dimethylethyl) 3-ethyl propanedioate, 1-tert-Butyl 3-ethyl malonate, 1-tert-Butyl 3-ethyl propanedioate, 3-O-tert-Butyl 1-O-ethyl propanedioate, Ethyl (2-tert-butoxycarbonyl)acetate, Ethyl 3-(tert-butoxy)-3-oxopropanoate, Ethyl T-Butyl Malonate, Ethyl Tert-Butyl Malonate, Malonic acid tert-butyl ethyl ester, NSC 69070, Propanedioic acid, 1,1-dimethylethyl ethyl ester-, Propanedioic acid, 1-(1,1-dimethylethyl) 3-ethyl ester, T-Butyl Ethyl Malonate, Tert-Butyl Ethyl Propanedioate
• CAS: 32864-38-3

Descripción

Tert-buty ethyl malonate is a catalyst that is used in the hydrogenation of aliphatic and aromatic carboxylic acids to their corresponding alcohols. This reaction proceeds through the insertion of the tertiary carbon atom into the double bond of the carboxylic acid. Tert-buty ethyl malonate is typically used in combination with an aluminium foil as a catalyst, which is then heated at 150°C for about three hours. Tert-buty ethyl malonate has been shown to be efficient in hydrogenating azide to amine. The reaction time can be shortened by using higher temperatures and pressures.

• Marca: Biosynth

Propiedades químicas

• Peso molecular: 188.22 g/mol
• Fórmula: C₉H₁₆O₄
• Pureza: Min. 95%
• InChI: InChI=1S/C9H16O4/c1-5-12-7(10)6-8(11)13-9(2,3)4/h5-6H2,1-4H3
• Clave InChI: InChIKey=OCOBFMZGRJOSOU-UHFFFAOYSA-N
• SMILES: CCOC(=O)CC(=O)OC(C)(C)C