(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
CAS: 55650-59-4
Ref. 3D-FD59975
1g | Descatalogado | ||
50mg | Descatalogado | ||
100mg | Descatalogado | ||
250mg | Descatalogado | ||
500mg | Descatalogado |
Información del producto
- (S)-(R)-BPPFA
- (2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)ferrocene
- (S)-N,N-Dimethyl-1-[(R)-1,2-bis(diphenylphosphino)ferrocenyl]ethylamine
- (S,R)-1-(1-dimethylaminoethyl)-1,2-*bis(diphenyl
- 1,2,3,4,5-cyclopentanepentayl, 1-[(1S)-1-(dimethylamino)ethyl]-2-(diphenylphosphino)-, compd. with 1-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
- Ferrocene, 1-[(1S)-1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, (2S)-
- Ferrocene, 1-[1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, [S-(R*,R*)]-
(S)-N,N-Dimethyl-1-[(R)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine is a phosphine complex that has been used in asymmetric hydrogenation of β-unsaturated carbonyl compounds. The reaction takes place in the presence of a chiral binap ligand and a catalyst to give the desired product and the corresponding alcohol. The reactions are stereospecific, with high selectivity for the desired product. The catalytic system can be applied to various types of substrates, including esters and carboxylic acids, with good results. This reaction is often used when there is an interaction between phosphine and carboxylic acid groups on the same molecule.