2,6-Bis(1,1-dimethylethyl)-4-ethylidene-2,5-cyclohexadien-1-one

CAS: 6738-27-8

Ref. TR-B429795

Información del producto

• Nombre: 2,6-Bis(1,1-dimethylethyl)-4-ethylidene-2,5-cyclohexadien-1-one
• Sinónimos: 2,6-Di-tert-butyl-4-ethylidene-2,5-cyclohexadien-1-one, NSC 14452, NSC 87400, 2,5-Cyclohexadien-1-one, 2,6-bis(1,1-dimethylethyl)-4-ethylidene-, 2,5-Cyclohexadien-1-one, 2,6-di-tert-butyl-4-ethylidene-, 2,6-Bis(1,1-dimethylethyl)-4-ethylidene-2,5-cyclohexadiene-1-on, 2,6-Bis(1,1-dimethylethyl)-4-ethylidene-2,5-cyclohexadiene-1-one, 2,6-Di-Tert-Butyl-4-Ethylidenecyclohexa-2,5-Dien-1-One, Nsc 14452, Nsc 87400

Descripción

Stability Light Sensitive
Applications 2,6-Bis(1,1-dimethylethyl)-4-ethylidene-2,5-cyclohexadien-1-one is a useful reagent for stereoselective catalytic 1,6-conjugate addition reaction of quinone methides with carbon-nucleophiles. It can also be utilized in Fe-catalyzed hydroalkylation of olefins with para-quinone methides.
References Chu, W., et al.: Angew. Chem. Int. Ed. 52, 9229 (2013); Shen, Y., et al. Org Lett. 18, 2722 (2016)

• Marca: TRC

Propiedades químicas

• Peso molecular: 232.36
• Fórmula: C₁₆H₂₄O
• Color/Forma: Off-White to Yellow Solid
• InChI: InChI=1S/C16H24O/c1-8-11-9-12(15(2,3)4)14(17)13(10-11)16(5,6)7/h8-10H,1-7H3
• Clave InChI: InChIKey=KEJPWCIDZLVYDJ-UHFFFAOYSA-N
• SMILES: CC=C1C=C(C(C)(C)C)C(=O)C(C(C)(C)C)=C1