Tubeimoside A

CAS: 102040-03-9

Ref. TR-T897030

Información del producto

• Nombre: Tubeimoside A
• Sinónimos: Olean-12-en-28-oic acid, 3-[[2-O-[4-O-[(3S)-4-carboxy-3-hydroxy-3-methyl-1-oxobutyl]-a-L-arabinopyranosyl]-ß-D-glucopyranosyl]oxy]-2,23-dihydroxy-, 28-(O-ß-D-xylopyranosyl-(1?3)-O-6-deoxy-a-L-mannopyranosyl-(1?2)-a-L-arabinopyranosyl) ester, intramol. 4''(3)?4''(28)-ester, (2ß,3ß,4a)-, Olean-12-en-28-oic acid, 3-[[2-O-[4-O-(4-carboxy-3-hydroxy-3-methyl-1-oxobutyl)-a-L-arabinopyranosyl]-ß-D-glucopyranosyl]oxy]-2,23-dihydroxy-, 28-(O-ß-D-xylopyranosyl-(1?3)-O-6-deoxy-a-L-mannopyranosyl-(1?2)-a-L-arabinopyranosyl) ester, intramol. ester, [2ß,3ß(S),4a]-, Lobatoside H, Tubeimoside 1, Tubeimoside I, Tuberimoside 1, (1S,4S,7R,8S,9R,11S,13S,14S,18S,21R,22R,23S,24R,25R,27R,28S,29S,30R,32R,34R,35S,37S,38S,41R,42R,46S,53S,54R,56S,57R)-7,8,18,22,23,24,28,29,35,57-decahydroxy-30,54-bis(hydroxymethyl)-13,18,37,41,42,46,48,48,53,54-decamethyl-56-{[(2S,3R,4S,5R)-3,4,5-trihydroxytetrahydro-2H-pyran-2-yl]oxy}-3,5,10,12,15,26,31,33,55-nonaoxadecacyclo[39.9.3.2~11,14~.1~21,25~.1~34,38~.0~1,46~.0~4,9~.0~27,32~.0~37,42~.0~45,53~]heptapentacont-44-ene-2,16,20-trione (non-preferred name), Olean-12-en-28-oic acid, 3-[[2-O-[4-O-(4-carboxy-3-hydroxy-3-methyl-1-oxobutyl)-α-<span class="text-smallcaps">L</smallcap>-arabinopyranosyl]-β-<smallcap>D</smallcap>-glucopyranosyl]oxy]-2,23-dihydroxy-, 28-(O-β-<smallcap>D</smallcap>-xylopyranosyl-(1→3)-O-6-deoxy-α-<smallcap>L</smallcap>-mannopyranosyl-(1→2)-α-<smallcap>L</span>-arabinopyranosyl) ester, intramol. ester, [2β,3β(S),4α]-, Olean-12-en-28-oic acid, 3-[[2-O-[4-O-[(3S)-4-carboxy-3-hydroxy-3-methyl-1-oxobutyl]-α-<span class="text-smallcaps">L</smallcap>-arabinopyranosyl]-β-<smallcap>D</smallcap>-glucopyranosyl]oxy]-2,23-dihydroxy-, 28-(O-β-<smallcap>D</smallcap>-xylopyranosyl-(1→3)-O-6-deoxy-α-<smallcap>L</smallcap>-mannopyranosyl-(1→2)-α-<smallcap>L</span>-arabinopyranosyl) ester, intramol. 4′′(3)→4′′(28)-ester, (2β,3β,4α)-, Tubelmosidea, Tubemoside A, hydroxy-3-methyl-1-oxobutyl)-α-L-arabinopyra, nosyl]-β-D-glucopyranosyl]oxy]-2,23-dihydroxy-,28-(O-β-D-xylopyranosyl-(1→3)-O-6-deoxy-α-L-mannopyranosyl-(1→2)-α-L-arabinopyranosyl)ester, intramol. ester, [2β,3β(S),4α]-

Descripción

Applications Tubeimoside A is an extract of tubeimoside, the bulb of Bolbostemma paniculatum, and is used in traditional Chinese medicine to treat tumors and to detoxify.
References Xu, Y. et al.: Chin. J. Canc. Res., 25, 312 (2013); Zhao, H. et al.: Chin. Sci. Bull., 33, 878 (2013);

• Marca: TRC

Propiedades químicas

• Peso molecular: 1319.43
• Fórmula: C₆₃H₉₈O₂₉
• Color/Forma: Neat
• InChI: InChI=1S/C63H98O29/c1-26-46-47(88-51-43(76)38(71)30(67)22-81-51)45(78)53(84-26)90-48-39(72)31(68)23-82-54(48)92-56(79)63-15-13-57(2,3)17-28(63)27-9-10-35-59(5)18-29(66)50(60(6,25-65)34(59)11-12-62(35,8)61(27,7)14-16-63)91-55-49(42(75)40(73)32(21-64)86-55)89-52-44(77)41(74)33(24-83-52)85-36(69)19-58(4,80)20-37(70)87-46/h9,26,28-35,38-55,64-68,71-78,80H,10-25H2,1-8H3/t26-,28-,29-,30+,31-,32+,33-,34+,35+,38-,39-,40+,41-,42-,43+,44+,45+,46-,47-,48+,49+,50-,51-,52+,53+,54+,55-,58-,59-,60-,61+,62+,63-/m0/s1
• SMILES: C[C@H]1O[C@@H]2OC3C(O)[C@@H](O)CO[C@H]3OC(=O)C34CCC(C)(C)C[C@H]3C3=CC[C@@H]5C6(C)C[C@H](O)[C@H](O[C@H]7O[C@H](CO)[C@@H](O)C(O)C7O[C@@H]7OC[C@H](OC(=O)C[C@@](C)(O)CC(=O)O[C@H]1C(O[C@@H]1OC[C@@H](O)C(O)C1O)C2O)C(O)C7O)[C@@](C)(CO)[C@@H]6CCC5(C)C3(C)CC4