CAS 6485-79-6
:Triisopropylsilane
Description :
Triisopropylsilane, avec le numéro CAS 6485-79-6, est un composé organosiliconé caractérisé par ses trois groupes isopropyles attachés à un atome de silicium. Ce composé est généralement un liquide incolore et volatil avec une odeur distinctive. Il est connu pour sa faible viscosité et son point d'ébullition relativement bas par rapport à d'autres silanes. Triisopropylsilane est souvent utilisé comme réactif dans la synthèse organique, en particulier dans les réactions d'hydrosilylation et comme groupe protecteur pour les alcools et les amines en raison de son encombrement stérique. Sa stabilité chimique et sa non-réactivité dans des conditions douces en font un composé précieux dans divers processus chimiques. De plus, il présente des propriétés hydrophobes, ce qui peut être avantageux dans des applications impliquant la modification de surfaces ou dans la formulation de matériaux à base de silicone. Des précautions de sécurité doivent être observées lors de la manipulation de ce composé, car il peut présenter des risques pour la santé s'il est inhalé ou ingéré. Dans l'ensemble, Triisopropylsilane est un composé polyvalent avec une utilité significative tant en chimie académique qu'industrielle.
Formule :C9H22Si
InChI :InChI=1/C9H22Si/c1-7(2)10(8(3)4)9(5)6/h7-10H,1-6H3
Code InChI :InChIKey=YDJXDYKQMRNUSA-UHFFFAOYSA-N
SMILES :[SiH](C(C)C)(C(C)C)C(C)C
Synonymes :- Silane, triisopropyl-
- Silane, tris(1-methylethyl)-
- Triisopropylhydrosilane
- Tripropan-2-Ylsilane
- Tris(1-methylethyl)silane
- Triisopropylsilane
- Tris-isopropylsilane
- SILANE IP3H
- Triisopropylsilane [Cas#
- (ME2CH)3SIH
- Triisopropylsilane ,97%
- TIS
- TIPS
- Voir plus de synonymes
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8 produits concernés.
Triisopropylsilane
CAS :Formule :C9H22SiDegré de pureté :>98.0%(GC)Couleur et forme :Colorless to Almost colorless clear liquidMasse moléculaire :158.36Triisopropylsilane, 98%
CAS :<p>Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the prep</p>Formule :C9H22SiDegré de pureté :98%Couleur et forme :Clear colorless, LiquidMasse moléculaire :158.36Triisopropylsilane
CAS :Formule :C9H22SiDegré de pureté :98%Couleur et forme :LiquidMasse moléculaire :158.3565Triisopropylsilane
CAS :TriisopropylsilaneFormule :C9H22SiDegré de pureté :98%Couleur et forme : clear. colourless liquidMasse moléculaire :158.35647g/molTriisopropylsilane
CAS :<p>S17975 - Triisopropylsilane</p>Formule :C9H22SiDegré de pureté :99%Couleur et forme :Clear LiquidMasse moléculaire :157.141Triisopropylsilane
CAS :Produit contrôlé<p>Applications Triisopropylsilane is used in the design of internalizing PSMA-specific Glu-ureido-based radiotherapeuticals for prostrate cancers. Reagent for the rational design of dual peptides targeting ghrelin and Y2 receptors to regulate food intake and body weight. Also functions as a highly selective reducing agent used in the preparation of anti-1,2-diols.<br> Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package<br>References Wuestemann, T., et al.: Theranostics, 6, 1085 (2016); Kilian, T., et al.: J. Med. Chem., 58, 4180 (2015); Horners, L.; et al.: Organomet. Chem., 282, 155 (1985)<br></p>Formule :C9H22SiCouleur et forme :NeatMasse moléculaire :158.36TRIISOPROPYLSILANE, 97%
CAS :<p>Trialkylsilyl Blocking Agent<br>Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.<br>Tri-substituted Silane Reducing Agent<br>Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.<br>Triisopropylsilane; Triisopropylsilylhydride; TIPS-H<br>Silylates strong acids with loss of hydrogenSilylates 1° alcohols selectivelySteric bulk allows for selective silylation of compounds with more than one hydroxyl groupSummary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochureVery sterically-hindered silaneBlocking agent forming derivatives stable in presence of Grignard reagentsSelectively silylates primary alcohols in presence of secondary alcoholsUsed as a cation scavenger in the deprotection of peptidesExtensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007<br></p>Formule :C9H22SiDegré de pureté :97%Couleur et forme :LiquidMasse moléculaire :158.36Triisopropylsilane
CAS :<p>Triisopropylsilane is a water-soluble analog of trifluoroacetic acid. It is used in the synthesis of peptides and other organic compounds. Triisopropylsilane has been shown to have significant cytotoxicity against cancer cells, with a half maximal inhibitory concentration (IC) of 0.1 mM. This compound also has the ability to chelate transition metals and is used as a fluorescence probe for metal ions. The pharmacokinetics of triisopropylsilane are dependent on its sodium-dependent glucose uptake and hydroxyl group metabolism. Triisopropylsilane binds to DNA and RNA, inhibiting their synthesis, which may be related to its antiviral activity against HIV infections.</p>Formule :C9H22SiDegré de pureté :Min. 95%Couleur et forme :Colorless Clear LiquidMasse moléculaire :158.36 g/mol
