CAS 694-53-1

Phénylsilane

Description :

Phénylsilane, avec le numéro CAS 694-53-1, est un composé organosiliconé caractérisé par la présence d'un groupe phényle attaché à un atome de silicium. Il apparaît généralement sous la forme d'un liquide incolore à jaune pâle avec une odeur distinctive. Ce composé est connu pour sa faible viscosité et sa volatilité, ce qui le rend utile dans diverses applications chimiques. Phénylsilane présente une réactivité due à la présence de liaisons Si-H, lui permettant de participer à des réactions d'hydrosilylation et de servir de précurseur pour des polymères de silicone. Sa structure chimique contribue à sa capacité à améliorer les propriétés thermiques et mécaniques des matériaux lorsqu'il est utilisé comme additif. De plus, Phénylsilane peut être utilisé dans la synthèse d'autres composés organosiliconés et dans des processus de modification de surface. Les considérations de sécurité incluent le maniement dans des zones bien ventilées et l'utilisation d'équipements de protection individuelle appropriés, car il peut être inflammable et irritant pour la peau et les yeux. Dans l'ensemble, Phénylsilane est un composé polyvalent avec des applications significatives en science des matériaux et en synthèse organique.

Formule : C₆H₈Si

InChI : InChI=1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3

Code InChI : InChIKey=PARWUHTVGZSQPD-UHFFFAOYSA-N

SMILES : [SiH3]C1=CC=CC=C1

Synonymes :

• Benzene, silyl-
• Fenilsilano
• Monophenylsilane
• Nsc 179699
• Phenylsilan
• Phenylsilane
• Silylbenzene
• Sip 6750.0
• Z 6047
• Silane, phenyl-
• Silane, phenyl-
• Fenylsilan

Phenylsilane

CAS : 694-53-1

Formule : C₆H₈Si

Degré de pureté : >96.0%(GC)

Couleur et forme : Colorless to Almost colorless clear liquid

Masse moléculaire : 108.22

Ref: 3B-P1291

Phenylsilane, 97%

CAS : 694-53-1

It is used as a pharmaceutical intermediate. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as

Formule : C₆H₇Si

Degré de pureté : 97%

Couleur et forme : Clear colorless, Liquid

Masse moléculaire : 107.21

Ref: 02-A17901

Silylbenzene

CAS : 694-53-1

Silylbenzene

Formule : C₆H₈Si

Degré de pureté : 97%

Couleur et forme : clear. colourless liquid

Masse moléculaire : 108.21322g/mol

Ref: 54-OR18813

Phenylsilane

CAS : 694-53-1

S13600 - Phenylsilane

Formule : C₆H₈Si

Degré de pureté : 97%

Couleur et forme : Liquid, Clear Liquid

Masse moléculaire : 108.215

Ref: 10-S13600

PHENYLSILANE

CAS : 694-53-1

Mono-substituted Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Trihydridosilane
Silyl Hydrides are a distinct class of silanes that behave and react very differently than conventional silane coupling agents. They react with the liberation of byproduct hydrogen. Silyl hydrides can react with hydroxylic surfaces under both non-catalyzed and catalyzed conditions by a dehydrogenative coupling mechanism. Trihydridosilanes react with a variety of pure metal surfaces including gold, titanium, zirconium and amorphous silicon, by a dissociative adsorption mechanism. The reactions generally take place at room temperature and can be conducted in the vapor phase or with the pure silane or solutions of the silane in aprotic solvents. Deposition should not be conducted in water, alcohol or protic solvents.
Phenylsilane; Silylbenzene
ΔHvap: 34.8 kJ/molEmployed in the reduction of esters to ethersReduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydrideReduces tin amides to tin hydridesUsed in the tin-catalyzed reduction of nitroalkanes to alkanesReduces α-halo ketones in presence of Mo(0)Adds to norbornene with high eeReducing reagent in radical reductionsYields ISiH3 on treatments with HI in presence of AlI3Extensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007

Formule : C₆H₈Si

Degré de pureté : 97%

Couleur et forme : Liquid

Masse moléculaire : 108.21

Ref: 3H-SIP6750.0

Phenylsilane

Produit contrôlé

CAS : 694-53-1

Applications Phenylsilane is used as a stoichiometric reductant for direct reductive amination of aldehydes and ketones. It is also used as nerve cell growth substrates in its polymer form.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Apodaca, Richard., et al.: Org. Lett., 3(11), 1745-1748 (2001); Gikonyo, Barnabas K., et al.: Polym. Chem., 47(1), 222 (2006)

Formule : C₆H₈Si

Couleur et forme : Neat

Masse moléculaire : 108.21

Ref: TR-P336775

Phenylsilane

CAS : 694-53-1

Phenylsilane is a model system for the study of the reaction mechanism of nucleophilic substitution. It is used to investigate the steric interactions between a substrate molecule and an electrophile that are important in determining the rate of reactivity. Phenylsilane has been shown to have antioxidative properties, which may be due to its ability to scavenge reactive oxygen species (ROS), such as hydroxyl radicals, superoxide ions, and hydrogen peroxide. Phenylsilane also has low kinetic energy and can form hydrogen bonds with carbonyl groups and amines. This chemical substance can react with quinoline derivatives, including benzoquinone, which is a toxic by-product of the metabolism of many drugs.

Formule : C₆H₈Si

Degré de pureté : Min. 95%

Couleur et forme : Clear Liquid

Masse moléculaire : 108.21 g/mol

Ref: 3D-FP45618