
CAS 69649-19-0
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Degré de pureté (%)
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100
1 produits concernés.
Pentacyclo[6.3.0.0(2,7).0(4,11).0(5,9)]undecan-3-one
CAS :Pentacyclo[6.3.0.0(2,7).0(4,11).0(5,9)]undecan-3-one is a polycyclic compound that has been postulated to be a thione derived from the desulfurization of pentacyclo[6.3.0.0(2,7).0(4,11).0(5,9)]undecane with dimethoxycarbene and toluene as reagents in the presence of a catalyst (Scheme 1). The stereoselective desulfurization of the lactams leads to the formation of either (1S) or (1R) products depending on the conditions used for the reaction. This reaction is thermally driven and occurs at 130°C under vacuum with a pressure of 10-2 Torr. The desulfurized product can then be converted into various esters by treatment with alcohols in the presence ofFormule :C11H12ODegré de pureté :Min. 95%Masse moléculaire :160.21 g/mol
