CAS 75-78-5

Dichlorodiméthylsilane

Description :

Dichlorodiméthylsilane, avec le numéro CAS 75-78-5, est un composé organosiliconé caractérisé par sa formule chimique C2H6Cl2Si. C'est un liquide incolore à jaune pâle avec une odeur piquante, couramment utilisé comme intermédiaire dans la synthèse de polymères de silicone et comme agent de couplage silane. Ce composé présente deux groupes méthyle et deux atomes de chlore attachés à un atome de silicium, ce qui contribue à sa réactivité. Dichlorodiméthylsilane est connu pour sa capacité à réagir avec l'eau, libérant de l'acide chlorhydrique et formant des composés de silanol, qui peuvent ensuite polymériser pour former des siloxanes. Il est modérément volatil et peut être dangereux, nécessitant une manipulation prudente en raison de sa nature corrosive et de ses effets potentiels sur la santé en cas d'exposition. En termes de propriétés physiques, il a un point d'ébullition relativement bas et une densité supérieure à celle de l'eau. En raison de sa réactivité et de son impact environnemental potentiel, des mesures de sécurité appropriées doivent être prises lors de la manipulation de cette substance dans des environnements de laboratoire ou industriels.

Formule : C₂H₆Cl₂Si

InChI : InChI=1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3

Code InChI : InChIKey=LIKFHECYJZWXFJ-UHFFFAOYSA-N

SMILES : [Si](C)(C)(Cl)Cl

Synonymes :

• Chlorodimethylsilane
• Dcdms
• Dichlor(dimethyl)silan
• Dichloro(dimethyl)silane
• Dichlorodimethylsilicon
• Dicloro(Dimetil)Silano
• Dimethyl dichlorosilane
• Dimethyldichlorosilane
• Dimethylsilane dichloride
• Dimethylsilyl dichloride
• Dmdcs
• Inerton AW-DMCS
• Ka 12
• Ka 22
• LS 130 (silane)
• Ls 130
• M 2
• M 2 (silane)
• Nsc 77070
• Repel-Silane
• Sid 4120.0
• Silane, Dichlorodimethyl
• Silanization Sol. Ii
• Silanization solution II
• Sylon Ct
• Tsl 8032

Dichlorodimethylsilane, 98+%

CAS : 75-78-5

Dichlorodimethylsilane is used to prepare a resin bound siloxane with tertiary alcohols and it is also used as a reagent for synthesis of optically active ansa-mettallocene polymerization catalysts. It acts as a precursor to silicone and polysilane compounds. It is also used in the glass coating to

Formule : C₂H₆Cl₂Si

Degré de pureté : 98+%

Couleur et forme : Liquid, Clear colorless to pale yellow

Masse moléculaire : 129.06

Ref: 02-L12133

Dimethyldichlorosilane, 99%

CAS : 75-78-5

Dimethyldichlorosilane, 99%

Formule : (CH₃)₂SiCl₂

Degré de pureté : 99%

Couleur et forme : colorless liq.

Masse moléculaire : 129.07

Ref: 08-93-1493

Dichlorodimethylsilane

CAS : 75-78-5

Dichlorodimethylsilane

Formule : C₂H₆Cl₂Si

Degré de pureté : 95%

Couleur et forme : clear. colourless liquid

Masse moléculaire : 129.06054g/mol

Ref: 54-OR46006

DIMETHYLDICHLOROSILANE, 99+% 5-GAL DRUM

CAS : 75-78-5

Bridging Silicon-Based Blocking Agent
Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.
Alkyl Silane - Conventional Surface Bonding
Aliphatic, fluorinated aliphatic or substituted aromatic hydrocarbon substituents are the hydrophobic entities which enable silanes to induce surface hydrophobicity. The organic substitution of the silane must be non-polar. The hydrophobic effect of the organic substitution can be related to the free energy of transfer of hydrocarbon molecules from an aqueous phase to a homogeneous hydrocarbon phase. A successful hydrophobic coating must eliminate or mitigate hydrogen bonding and shield polar surfaces from interaction with water by creating a non-polar interphase. Although silane and silicone derived coatings are in general the most hydrophobic, they maintain a high degree of permeability to water vapor. This allows coatings to breathe and reduce deterioration at the coating interface associated with entrapped water. Since ions are not transported through non-polar silane and silicone coatings, they offer protection to composite structures ranging from pigmented coatings to rebar reinforced concrete. A selection guide for hydrophobic silanes can be found on pages 22-31 of the Hydrophobicity, Hydrophilicity and Silane Surface Modification brochure.
Dimethyldichlorosilane; Dichlorodimethylsilane; DMS
AIR TRANSPORT FORBIDDENRedistilledViscosity: 0.47 cStVapor pressure, 17 °C: 100 mmSpecific heat: 0.92 J/g/°ΔHcomb: -2,055 kJ/molΔHvap: 33.5 kJ/molSurface tension: 20.1 mN/mCoefficient of thermal expansion: 1.3 x 10-3Critical temperature: 247.2 °CCritical pressure: 34.4 atmFundamental monomer for siliconesEmployed in the tethering of two olefins for the cross metathesis-coupling step in the synthesis of Attenol AAids in the intramolecular Pinacol reactionReacts with alcohols, diols, and hydroxy carboxylic acidsEmployed as a protecting group/template in C-glycoside synthesisAvailable in a lower purity as SID4120.0Summary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure

Formule : C₂H₆Cl₂Si

Degré de pureté : 99+%

Couleur et forme : Straw Liquid

Masse moléculaire : 129.06

Ref: 3H-SID4120.1

DIMETHYLDICHLOROSILANE, 98%

CAS : 75-78-5

Bridging Silicon-Based Blocking Agent
Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.
Alkyl Silane - Conventional Surface Bonding
Aliphatic, fluorinated aliphatic or substituted aromatic hydrocarbon substituents are the hydrophobic entities which enable silanes to induce surface hydrophobicity. The organic substitution of the silane must be non-polar. The hydrophobic effect of the organic substitution can be related to the free energy of transfer of hydrocarbon molecules from an aqueous phase to a homogeneous hydrocarbon phase. A successful hydrophobic coating must eliminate or mitigate hydrogen bonding and shield polar surfaces from interaction with water by creating a non-polar interphase. Although silane and silicone derived coatings are in general the most hydrophobic, they maintain a high degree of permeability to water vapor. This allows coatings to breathe and reduce deterioration at the coating interface associated with entrapped water. Since ions are not transported through non-polar silane and silicone coatings, they offer protection to composite structures ranging from pigmented coatings to rebar reinforced concrete. A selection guide for hydrophobic silanes can be found on pages 22-31 of the Hydrophobicity, Hydrophilicity and Silane Surface Modification brochure.
Dimethyldichlorosilane; Dichlorodimethylsilane; DMS
AIR TRANSPORT FORBIDDENViscosity: 0.47 cStVapor pressure, 17 °C: 100 mmSpecific heat: 0.92 J/g/°ΔHcomb: -2,055 kJ/molΔHvap: 33.5 kJ/molSurface tension: 20.1 mN/mCoefficient of thermal expansion: 1.3 x 10-3Critical temperature: 247.2 °CCritical pressure: 34.4 atmFundamental monomer for siliconesEmployed in the tethering of two olefins for the cross metathesis-coupling step in the synthesis of Attenol AAids in the intramolecular Pinacol reactionReacts with alcohols, diols, and hydroxy carboxylic acidsEmployed as a protecting group/template in C-glycoside synthesisHigher purity available as SID4120.1Summary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure

Formule : C₂H₆Cl₂Si

Degré de pureté : 98%

Couleur et forme : Straw Amber Liquid

Masse moléculaire : 129.06

Ref: 3H-SID4120.0

Dichlorodimethylsilicon

Produit contrôlé

CAS : 75-78-5

Applications Dichlorodimethylsilicon is a organosilicon compound and is the precursor to dimethylsilicone and polysilane compounds.
E0
References Tsekova, D., et al.: Chem. Engineer. Sci., 77, 201 (2012); Mujawar, L.H., et al.: Analyst., 138. 518 (2013);

Formule : C₂H₆Cl₂Si

Couleur et forme : Neat

Masse moléculaire : 129.06

Ref: TR-D434475

Dichlorodimethylsilane

CAS : 75-78-5

Dichlorodimethylsilane is a chemical compound that belongs to the group of organic compounds that are solids at room temperature. It has been used as a model system for studying the hydrophobic effect, and has also been shown to be an efficient solid catalyst for hydrogenation reactions. Dichlorodimethylsilane can be used in analytical chemistry as it is soluble in water, and it can be used as a reaction solution for potassium dichromate. The reaction mechanism for dichlorodimethylsilane is yet to be determined, but it is believed that the hydroxyl group on one molecule reacts with the hydrogen on another molecule.

Formule : C₂H₆Cl₂Si

Degré de pureté : Min. 95%

Masse moléculaire : 129.06 g/mol

Ref: 3D-FD46987

Dimethyl Dichlorosilane (DMDCS) pure, 98%

CAS : 75-78-5

Formule : C₂H₆Cl₂Si

Degré de pureté : min. 98%

Couleur et forme : Clear, Colourless to pale yellow, Liquid

Masse moléculaire : 129.06

Ref: SR-21800