mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

CAS : 67719-69-1

Ref. 02-044506

Informations sur le produit

• Nom: mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene
• Synonymes: tebbe's reagent, Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium, Chlorobishetacyclopentadienyldimethylammoniummumethyle, MU-Chlorobis(Eta5-cyclopentadienyl)(dimethylaluminum)-MU-methylene-titanium (ca. 0.5mol/l Toluene Soln.), Methane, aluminum-titanium complex, Reagents, Tebbe, Tebbe reagent, Tebbe's reagent, Titanium, μ-chlorobis(η⁵-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylene-, mu-Chlorobis(((heta)^5)-cyclopentadienyl)(dimethylammonium)-mu-methylene-titanium, μ-Chlorobis(η⁵-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium

Description

μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Marque: Alfa Aesar By Thermo Fisher Scientific

Propriétés chimiques

• Masse moléculaire: 284.59
• Formule: C₁₃H₁₈AlClTi
• Couleur/Forme: Red to dark red to purple, Solution
• Code InChI: HIVIAXIRSNAVAD-UHFFFAOYSA-M