2-Methylanisole, 99%

CAS : 578-58-5

Ref. 02-A13897

Informations sur le produit

• Nom: 2-Methylanisole, 99%
• Synonymes: 2-methylanisole, 1-Methoxy-2-Methyl-Benzene, 1-Methoxy-2-methylbenzene, 1-Methoxy-3-Methyl-Benzene, 1-Methoxy-4-Methyl-Benzene, 2-Cresol methyl ether, 2-MethoxyToluene/2-Methyl Anisole, 2-Methoxytoluene, 2-Methyl-1-methoxybenzene, Anisole, o-methyl-, Benzene, 1-methoxy-2-methyl-, Methyl o-cresyl ether, Methyl o-methylphenyl ether, Methyl o-tolyl ether, NSC 6253, Nk 409, o-Cresol methyl ether, o-Cresyl methyl ether, o-Cresyl methyl ether~2-Methoxytoluene, o-Methoxytoluene, o-Methylanisole

Description

The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Marque: Alfa Aesar By Thermo Fisher Scientific

Propriétés chimiques

• Masse moléculaire: 122.17
• Formule: C₈H₁₀O
• Degré de pureté: 99%
• Couleur/Forme: Clear colorless to pale yellow, Liquid
• InChI: InChI=1S/C8H10O/c1-7-5-3-4-6-8(7)9-2/h3-6H,1-2H3
• Code InChI: DTFKRVXLBCAIOZ-UHFFFAOYSA-N
• SMILES: COc1ccccc1C