(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

CAS : 155830-69-6

Ref. 3D-FD179855

Informations sur le produit

• Nom: (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
• Synonymes: (R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph, (R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine, Josiphos SLJ002-1, 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1), (R)-1-[(S)-2-(Dipheny1phosphino)ferroceny1] ethyldi-tert-butylphosphine, (R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine

Description

A novel, practical and efficient method for the preparation of (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine is described. The asymmetric synthesis of ketones with high enantiomeric excess was achieved using this ligand in a one-pot, two-step procedure. The homogeneous catalytic reduction of nitriles to primary amines was also demonstrated. This methodology is applicable to the preparation of other chiral phosphines and phosphine derivatives.

• Marque: Biosynth

Propriétés chimiques

• Masse moléculaire: 542.5 g/mol
• Formule: C₃₂H₄₀FeP₂
• Degré de pureté: Min. 98 Area-%
• Couleur/Forme: Powder