(5S)-3,4,5,6-Tetrahydro-5-phenyl-4(h)-1,4-oxazin-2-one
CAS : 144896-92-4
Ref. 3D-FT148618
| Taille indéfinie | À demander |
Informations sur le produit
- (5S)-3,4,5,6-Tetrahydro-5-Phenyl-2(H)-1,4-Oxazin-2-One
- S-5-Phenyl-Morpholin-2-One
- (5S)-3,4,5,6-(S)-5-Phenylmorpholin-2-one
- (5S)-5-phenylmorpholin-2-one
The asymmetric synthesis of (5S)-3,4,5,6-Tetrahydro-5-phenyl-4(h)-1,4-oxazin-2-one has been accomplished by a 1,3-dipolar cycloaddition of an iminium ion with a chiral aliphatic aldehyde. The diastereoselectivity was controlled by the transition state geometry and stereochemical outcome of the 1,3-dipolar cycloaddition.
Aldehydes are stabilized in hydrochloric acid because of its electrophilic nature. This makes it possible to conduct asymmetric syntheses with them.
The molecule is chiral because it contains a carbon atom that has four different substituents on it. It can be classified as an enantiopure molecule because it has two enantiomers that are not superimposable on each other.
Propriétés chimiques
Question d’ordre technique sur : 3D-FT148618 (5S)-3,4,5,6-Tetrahydro-5-phenyl-4(h)-1,4-oxazin-2-one
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