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Trifluoromethanesulfonyl bromide is a perhalogenated organic compound that has the chemical formula CF3SO2Br. It is an inorganic base and a fluorinating agent. Trifluoromethanesulfonyl bromide reacts with hydrogen fluoride to produce triflic acid, which can then react with organic compounds to produce perfluoroalkyl and alkynyl groups. Trifluoromethanesulfonyl bromide is often used as a reagent for the preparation of perhalogenated compounds.