POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 15-25 cSt

CAS : 63148-57-2

Ref. 3H-HMS-991

Informations sur le produit

• Nom: POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 15-25 cSt
• Synonymes: Abil OSW 5, Akophob SN, Alkasil MH 1667, Blue Star 202, Bluesil 269, Bluesil 628V12H3.5, Bluesil Emulsion 269, Bluesil WR 68, Bs 4004, By 11-003, By 22-861, C 25B, Dx 1202-60, Dy-H 212-40, F 1-3546, Fz 3702, Hmq 30, Hv 70, Kf 99-20Cs, Khs 202A, Lightsilicone P 290E, Lightsilicone P 316, Lighttex S 011, Lukooil H, Ly-H 075, Me hydrogen silicones, Me hydrogen siloxanes, Me hydrogen trimethylsilyl-terminated polysiloxanes, Methyl Hydrogen Silicone Fluid, Methyl hydro-silicone oil, Methyl hydrogen polysiloxane, Methylhydro-silicone oil, Mh 30, Momentive SS 4300, Mq 103, Mqh 7, NH 30 (siloxane), NR-B (siloxane), Nh 2101, Nh 30, Nh 31, Nh 32, Ns 5802, Ns 5805, NuSil MED 6345B, Org 202, Pmhs, Poly(dimethylsiloxane-co-methylhydrosiloxane), Poly(methylhydrosiloxane), Polymethylhydrosiloxane, Trimethylsiloxy Terminated, Polysiloxanes, Me hydrogen, Q 2-5057S, Q 2-5567S, RD 1 (crosslinker), Rhodorsil RTV 141B, Rtv 141B, Sb 04, Sda 3211, Sda 3211-2, Sf 6000P, Sf 6001P, Sf 6004P, Sh 1007, Sh 2002, Sh 21, Si 202, Si 4087, Silastic RD 1, Silikon HV 70, Siloprene U 430, Siloxanes and Silicones, Me hydrogen, Silres BS 1042, Silres BS 4004, Silres SY 816VP, Siltex 02, Sm 8707Ex, Spbd 81943, Spbd 88017, Ss 4300, Tegiloxan PTF 16, Tegopren 6846, Tegosivil LHZ, Tegosivin T 110, Thp 11A, Trimethylsiloxy terminatedpolymethyhydrosiloxane, Ts-D 120, Tsf 484Ex, Tsw 83, U 430, Ultratex EA, Ultratex EW, V 93 (siloxane), Ws 60E, X 21-5953, X 40-2664F, Xf 40A6098, Xhg 202, Xhg 202-100, Xl 321
• CAS: 63148-57-2

Description

Siloxane-Based Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Pendant Functional Fluid; polyMethylHydrosiloxanes, TMS Terminated
MethylHydrosiloxane homopolymers are used as water-proofing agents, reducing agents and as components in some foamed silicone systems.
Poly(methylhydrosiloxane); Methyl hydrogen siloxane; Polysiloxanes, methyl hydrogen; Siloxanes and silicones, methyl hydrogen
Viscosity: 15-25 cStMolecular Weight: 1,400-1,800 g/molMol% Hydride: 100Reduces lactones to lactolsReduces aldehydes, ketones, esters, lactones, triglycerides and epoxides to alcohols with zinc hydride catalysisWith titanium tetraisopropoxide catalysis carries out reductive amination of ketones and aldehydes and the reduction of acids or esters to 1° alcoholsWith TBAF catalysis selectively reduces aldehydes over ketonesUsed to generate tri-n-butyltin hydride ‘in-situ’ and in a one-pot hydrostannylation/Stille coupling sequenceReduces esters to alcoholsExtensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007

• Marque: Gelest

Propriétés chimiques

• Masse moléculaire: 1400-1800
• Couleur/Forme: Liquid