Informations sur le produit
- (Methylsilyl)benzene
- Benzene, (methylsilyl)-
- Benzylsilane
- Methyl-Phenyl-Silicon
- Methylphenylsilane
- Silane, methylphenyl-
- Phenylmethylsilane
Dialkyl Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Phenylmethylsilane; Methylphenylsilane
Used in the preparation of silyl-substituted alkylidene complexes of tantalumUsed in the preparation of vicinal diaminesExtensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007
