Informations sur le produit
- Nsc 408673
- Potassium trimethylsiloxide
- Potassium trimethylsilyloxide
- Potassium, (trimethylsiloxy)-
- Silanol, 1,1,1-trimethyl-, potassium salt (1:1)
- Silanol, trimethyl-, potassium deriv.
- Silanol, trimethyl-, potassium salt
- Trimethylsilanol potassium salt
- Trimethylsiloxypotassium
Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Potassium trimethylsilanolate; Potassium trimethylsiloxide; Trimethylsilanol, potassium salt
Contains potassium hydroxide, hexamethyldisiloxaneCatalyst for the cross-coupling of aryl and vinylsilanesInitiates silicone (cyclic siloxane) polymerizationsCleaves esters under non-aqueous conditionsCatalyzes fluoride-free, silicon-based cross-coupling reactionsConverts difluorobenzenes to fluorophenolsExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
