[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium

CAS : 301224-40-8

Ref. TR-B588655

Informations sur le produit

• Nom: [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium
• Synonymes: (SP-5-41)-[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-?O)phenyl]methylene-?C]ruthenium, (1,3-Dimesityl-2-imidazolidinylidene)(o-isopropoxyphenylmethylene)ruthenium Dichloride, Grubbs-Hoveyda 2nd Generation Catalyst, Grubbs-Hoveyda Catalyst, Hoveyda II Catalyst, Hoveyda Catalyst, Hoveyda Second Generation Catalyst, Hoveyda-Grubbs 2nd Generation Catalyst, Hoveyda-Grubbs Catalyst, Hoveyda-Grubbs Catalyst 2nd. Generation, Hoveyda-Grubbs Second Generation Catalyst, Second Generation Hoveyda Grubbs Catalyst, Second-generation Hoveyda Catalyst, (1,3-Bis-(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene)Dichloro(O-Isopropoxyphenylmethylene)Ruthenium, (1,3-Dimesityl-2-imidazolidinylidene)(o-isopropoxyphenylmethylene)ruthenium dichloride, (SP-5-41)-[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]ruthenium, C 627, Grubbs 2nd catalyst, Grubbs-Hoveyda 2nd generation catalyst, Grubbs-Hoveyda catalyst, Hoveyda II catalyst, Hoveyda catalyst, Hoveyda grubbs II catalyst, Hoveyda second generation catalyst, Hoveyda-Grubbs 2nd generation catalyst, Hoveyda-Grubbs Catalyst 2nd, Hoveyda-Grubbs catalyst, Hoveyda-Grubbs second generation catalyst, Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]-, (SP-5-41)-, Second generation Hoveyda Grubbs catalyst, Second-generation Hoveyda catalyst, [1,3-Bis(2,4,6-Trimethylphenyl)Imidazolidin-2-Ylidene](Dichloro){[2-(1-Methylethoxy)Phenyl]Methylidene}Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)phenyl]methylene-κC]ruthenium

Description

Applications [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium is a cross-metathesis catalyst used for installation of S-allylcysteine in proteins for enabling olefin metathesis on proteins.
References Lin, Y.A., et al.: J. Am. Chem. Soc., 132, 16805 (2010); Chalker, J.M., et al.: Chem. Comm., no vol., 3714 (2009)

• Marque: TRC

Propriétés chimiques

• Masse moléculaire: 626.62
• Formule: C₃₁H₃₈Cl₂N₂ORu
• Couleur/Forme: Neat
• InChI: InChI=1S/C21H26N2.C10H12O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
• Code InChI: InChIKey=ZRPFJAPZDXQHSM-UHFFFAOYSA-L
• SMILES: Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2OC(C)C)c(C)c1