2-​(Chloromethyl)​allyl-​trimethylsilane

CAS : 18388-03-9

Ref. TR-C371430

Informations sur le produit

• Nom: 2-​(Chloromethyl)​allyl-​trimethylsilane
• Synonymes: 2-Chloromethyl-3-trimethylsilyl-1-propene, 2-Chloromethyl-3-trimethylsilylpropene, 2-(Chloromethyl)allyl-trimethylsilane, 1-Bromooct-2-Yne

Description

Stability Moisture Sensitive
Applications 2-​(Chloromethyl)​allyl-​trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-​(Chloromethyl)​allyl-​trimethylsilane was used in catalytic Sakurai reaction of α,​β-​enones.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Kopecky, D., et al.: J. Am. Chem. Soc., 123, 8420 (2001).Lee, P., et al.: J. Org. Chem., 66, 8646 (2001).

• Marque: TRC

Propriétés chimiques

• Masse moléculaire: 306.337
• Formule: C₁₄H₁₄N₂O₄S
• Couleur/Forme: Neat
• InChI: InChI=1S/C14H14N2O4S/c1-6-3-4-8(5-15-6)11-10(14(19)20)16-12(18)9(7(2)17)13(16)21-11/h3-5,7,9,13,17H,1-2H3,(H,19,20)/t7-,9+,13-/m1/s1
• Code InChI: InChIKey=WYJQBZUHDURGNF-BZTNIEFMSA-N
• SMILES: Cc1ccc(C2=C(C(=O)O)N3C(=O)[C@H]([C@@H](C)O)[C@H]3S2)cn1