(Diacetoxyiodo)benzene

CAS : 3240-34-4

Ref. TR-D360500

Informations sur le produit

• Nom: (Diacetoxyiodo)benzene
• Synonymes: (Dihydroxyiodo)benzene, BAIB, Bis(acetato)phenyliodine, Bis(acetato-?O)phenyliodine, Diacetoxy(phenyl)iodine, Iodobenzene Diacetate, Iodophenyl Diacetate, Iodosobenzene Diacetate, Iodosylbenzene Diacetate, NSC 226375, NSC 23801, PIDA, Phenyliodine Diacetate, Phenyliodine(III) Diacetate, Phenyliodo Diacetate, Phenyliodonium Diacetate, Phenyliodoso Acetate, Phenyliodoso Diacetate, Phenyliodosyl Diacetate, [Bis(acetoxy)iodo]benzene, Iodosodiacetate Benzene, Baib, Benzene, (diacetoxyiodo)-, Benzene, (dihydroxyiodo)-, diacetate, Benzene, iodoso-, diacetate, Bis(Acetyloxy)(Phenyl)-Lambda~3~-Iodane, Bis(acetato-O)phenyliod, Bis(acetato-O)phenyliode, Bis(acetato-κO)phenyliodine, Diacetoxyiodo-Benzen, Iodine, bis(acetato-O)phenyl-, Iodine, bis(acetato-κO)phenyl-, Iodobenzene-Acetic Acid (1:2), Iodonium, (acetyloxy)phenyl-, Iodophenyl diacetate, Iodosobenzene diacetate, Iodosylbenzene Di(Acetate), Iodosylbenzene diacetate, Nsc 226375, Nsc 23801, PIA, Phenyliodine(III) diacetate, Phenyliodo diacetate, Phenyliodonium diacetate, Phenyliodoso acetate, Phenyliodoso diacetate, Phenyliodosyl diacetate, Pida, bis(acetato-O)feniliodo, bis(acetato-O)phenyliodine

Description

Stability Light and Moisture sensitive
Applications (Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.
References Telvekar, V.N., et al.: Synlett., 2778 (2012); Liu, W.B., et al.: Beilstein. J. Org. Chem., 8, 244 (2012);

• Marque: TRC

Propriétés chimiques

• Masse moléculaire: 322.1
• Formule: C₁₀H₁₁IO₄
• Couleur/Forme: White Solid
• InChI: InChI=1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
• Code InChI: InChIKey=ZBIKORITPGTTGI-UHFFFAOYSA-N
• SMILES: CC(=O)OI(OC(C)=O)c1ccccc1