3-O-[(1,1-Dimethylethyl)dimethylsilyl]-1,2:5,6-bis-O-(1-methylethylidene)-α-D-glucofuranose

CAS : 99605-27-3

Ref. TR-D610870

Informations sur le produit

• Nom: 3-O-[(1,1-Dimethylethyl)dimethylsilyl]-1,2:5,6-bis-O-(1-methylethylidene)-α-D-glucofuranose
• Synonymes: Furo[2,3-d]-1,3-dioxole a-D-Glucofuranose Deriv.

Description

Applications 3-O-[(1,1-Dimethylethyl)dimethylsilyl]-1,2:5,6-bis-O-(1-methylethylidene)-α-D-glucofuranose is an intermediate used in the synthesis of (5E)-5,6-Dideoxy-3-O-[(1,1-dimethylethyl)dimethylsilyl]-1,2-O-(1-methylethylidene)-6-nitro-α-D-xylo-hex-5-enofuranose (D495405), which can be used in the synthesis of Pancratistatin (P173600), an anti-cancer compound that initiates cell-death in cancer cells.
References McLachlan, A. et al.: Apoptosis, 10, 619 (2005);

• Marque: TRC

Propriétés chimiques

• Masse moléculaire: 374.54
• Formule: C₁₈H₃₄O₆Si
• Couleur/Forme: Neat
• InChI: InChI=1S/C18H34O6Si/c1-16(2,3)25(8,9)24-13-12(11-10-19-17(4,5)21-11)20-15-14(13)22-18(6,7)23-15/h11-15H,10H2,1-9H3/t11-,12-,13+,14-,15-/m1/s1
• Code InChI: InChIKey=LFPYKSVBKNNGCK-UXXRCYHCSA-N
• SMILES: CC1(C)OC[C@H]([C@H]2O[C@@H]3OC(C)(C)O[C@@H]3[C@H]2O[Si](C)(C)C(C)(C)C)O1