CAS 12354-84-6

Iridio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di-

Descrizione:

Iridio, di-μ-clorodiclorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentametil-2,4-ciclopentadien-1-il]di- è un composto organometallico complesso che presenta l'iridio come atomo centrale di metallo. Questo composto è caratterizzato dalla sua coordinazione con più leganti, specificamente cloruri e derivati del ciclopentadiene, che contribuiscono alle sue uniche proprietà strutturali ed elettroniche. La presenza dei sostituenti pentametilici sugli anelli di ciclopentadiene migliora la stabilità e la solubilità del complesso. I complessi di iridio sono noti per le loro proprietà catalitiche, in particolare nella sintesi organica e nel campo della scienza dei materiali. Il ponte di-μ-cloro indica che i cloruri stanno agendo come leganti di ponte tra i centri di iridio, il che può influenzare la reattività e l'ambiente di coordinazione del metallo. In generale, questo composto esemplifica l'intricata interazione tra metallo e legante che definisce il comportamento dei complessi di metalli di transizione in varie applicazioni chimiche.

Formula: C₂₀H₃₀Cl₄Ir₂

InChI: InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4

InChI key: InChIKey=MMAGMBCAIFVRGJ-UHFFFAOYSA-J

SMILES: [Cl-][Ir+3]12345(C=6(C)C1(C)=C2(C)[C-]3(C)C46C)[Cl-][Ir+3]789%10([Cl-])([Cl-]5)[C-]%11(C)C7(C)=C8(C)C9(C)=C%10%11C

Sinonimi:

• (Ir(Cp*)Cl₂)₂
• (Pentamethylcyclopentadienyl)iridium dichloride dimer
• (Pentamethylcyclopentadienyl)iridium(III)Dichloride Dimer
• (η⁵-Pentamethylcyclopentadienyl)iridium dichloride dimer
• 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, iridium complex
• Bis((μ-chloro)chloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(chloro(μ₂-chloro)(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(dichloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Bis(dichloro(η⁵-η-pentamethylcyclopentadienyl)iridium)
• Bis(pentamethylcyclopentadiene)tetrachlorodiiridium
• Bis(pentamethylcyclopentadienyliridium dichloride)
• Bis(μ-chloro)bis[chloro(η⁵-pentamethylcyclopentadienyl)iridium]
• Bis[dichloro(pentamethylcyclopentadienyl)iridium]
• Di-μ-chlorobis(chloro(η⁵-pentamethylcyclopentadienyl)iridium)
• Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)diiridium
• Dichloro(pentamethylcyclopentadienyl)iridium dimer
• Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
• Dichlorobis(μ₂-chloro)bis(η⁵-pentamethylcyclopentadienyl)diiridium
• Dichlorodi-μ-chlorobis(η⁵-pentamethylcyclopentadienyl)diiridium
• Dichloropentamethylcyclopentadienyliridiumdimer
• Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
• Pentamethylcyclopentadienyl)iridium(III) chloride dimer
• Pentamethylcyclopentadienyliridium(III) chloride,dimer
• Pentamethylcyclopentadienyliridium(III) dichloride dimer
• Tetrachlorobis(pentamethylcyclopentadienyl)diiridium
• Tetrachlorobis(η⁵-pentamethylcyclopentadienyl)diiridium

(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer

CAS: 12354-84-6

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: >95.0%(T)

Colore e forma: Light yellow to Brown powder to crystal

Peso molecolare: 796.69

Ref: 3B-P1763

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some

Formula: C₂₀H₃₀Cl₄Ir₂

Colore e forma: Orange, Crystals or crystalline powder

Peso molecolare: 796.69

Ref: 02-045565

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%

Formula: (CH₃)₅C₅IrCl₂

Purezza: 98%

Colore e forma: orange xtl.

Peso molecolare: 796.67

Ref: 08-77-1060

Iridium,di-m-chlorodichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-

CAS: 12354-84-6

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: 98%

Colore e forma: Solid

Peso molecolare: 796.6982

Ref: IN-DA00HHBN

(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer

CAS: 12354-84-6

(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: 98%,Ir:48%,high pure

Colore e forma: orange powder

Peso molecolare: 796.70g/mol

Ref: 54-OR49087

Pentamethylcyclopentadienyliridium(III) chloride, dimer

CAS: 12354-84-6

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: ≥ 97.0%

Colore e forma: Yellow to orange powder

Peso molecolare: 796.70

Ref: 7W-GX6497

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

Prodotto controllato

CAS: 12354-84-6

Applications Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is commonly found to be used as a catalyst in reactions, and the synthesis oxidative arylation with indoles, azobenzene derivatives., and ortho-​alkynylated arylalkylamines.
References Li, G., et al.: Org. Lett., 20, 2454-58 (2018); Tindall, D.J., et al.: J. Am. Chem. Soc., 140, 1884-93 (2018); Chen, X., et al.: Org. Lett., 20, 1171-74 (2018);

Formula: C₂₀H₃₀Cl₄Ir₂

Colore e forma: Neat

Peso molecolare: 796.7

Ref: TR-D438770

DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) DIMER

CAS: 12354-84-6

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: 98%

Peso molecolare: 796.69

Ref: 10-F053213

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS: 12354-84-6

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer (DCPI) is a synthetic ligand that can be used in biomolecular and chemical applications. DCPI has been shown to be stable in the presence of chloride, which is needed for many catalytic reactions. This compound has high activity as a transfer agent and is also able to transfer amines and cyclic compounds. DCPI can be used in fluorescence-based assays, due to its strong fluorescence emission.

Formula: C₂₀H₃₀Cl₄Ir₂

Purezza: Min. 95%

Colore e forma: Powder

Peso molecolare: 796.7 g/mol

Ref: 3D-FD55182