CAS 14647-23-5

(Bis(difenilfosfino)etano)dicloro nichel

Descrizione:

(Bis(difenilfosfino)etano)dicloro nichel, comunemente noto come NiCl2(dppeth), è un composto di coordinazione che presenta nichel in uno stato di ossidazione +2 coordinato a due leganti di difenilfosfinoetano e due ioni cloruro. Questo composto tipicamente mostra una geometria quadrata planare a causa della configurazione elettronica d8 del nichel, che è caratteristica di molti complessi di nichel(II). I leganti di difenilfosfinoetano contribuiscono alla stabilità e solubilità complessiva del complesso in solventi organici. NiCl2(dppeth) è spesso utilizzato nella catalisi, in particolare in reazioni di accoppiamento incrociato e altre trasformazioni organiche, grazie alla sua capacità di facilitare il trasferimento di elettroni e promuovere la formazione di legami. La presenza di atomi donatori di fosforo aumenta la reattività del centro di nichel, rendendolo un composto importante nella chimica organometallica. Inoltre, il composto può mostrare interessanti proprietà termiche e fotocatalitiche, che possono essere rilevanti in varie applicazioni, inclusa la scienza dei materiali e la catalisi.

Formula: C₂₆H₂₄Cl₂NiP₂

InChI: InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key: InChIKey=XXECWTBMGGXMKP-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Sinonimi:

• (Bis(diphenylphosphino)ethane)dichloronickel
• 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
• 1,2-Bis(diphenylphosphino)ethanedichloronickel
• 1,2-Bis(diphenylphosphino)ethanenickel dichloride
• 1,2-Ethylenebis(diphenylphosphine)nickel dichloride
• DPPE.NiCl2
• Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
• Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
• Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]nickel
• Dichloro[1,2-ethanediylbis[diphenylphosphine]]nickel
• Dichloro[ethylenebis[diphenylphosphine]]nickel
• Dichlorobis[(diphenylphosphino)ethane]nickel(II)
• Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine-κP]]-, (SP-4-2)-
• Nickel, dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P′]-, (SP-4-2)-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-
• Nickel, dichloro[ethylenebis[diphenylphosphine]]-, cis-
• Phosphine, 1,2-ethanediylbis[diphenyl-, nickel complex
• [1,2-Bis(Diphenylphosphino)Ethane]Dichloronickel(Ii)
• [1,2-Bis(diphenylphosphino)ethane]dichloronickel

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purezza: >96.0%(T)

Colore e forma: Orange to Amber to Dark red powder to crystal

Peso molecolare: 528.02

Ref: 3B-B2225

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS: 14647-23-5

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols

Formula: C₂₆H₂₄Cl₂NiP₂

Purezza: 98%

Colore e forma: Orange-red to brown, Powder

Peso molecolare: 528.02

Ref: 02-013932

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purezza: 98%

Colore e forma: Solid

Peso molecolare: 528.0157

Ref: IN-DA0032KC

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

CAS: 14647-23-5

1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride

Purezza: 98%

Peso molecolare: 528.02g/mol

Ref: 54-IN10319

[Bis(diphenylphosphino)ethane]dichloronickel

Prodotto controllato

CAS: 14647-23-5

Applications [Bis(diphenylphosphino)ethane]dichloronickel is a coordination complex with potential antitumor activity. It is also used as a fast and efficient hydrogen production catalyst.
References Mirabelli, C.K., et al.: J. Med. Chem., 30, 2181 (1987); Gan, L., et al.: J. Am. Chem. Soc., 137, 1109 (2015)

Formula: C₂₆H₂₄Cl₂NiP₂

Colore e forma: Neat

Peso molecolare: 528.02

Ref: TR-B430455

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

CAS: 14647-23-5

Formula: C₂₆H₂₄Cl₂NiP₂

Purezza: 96%

Colore e forma: Solid, Yellow red - deep yellow red powder

Peso molecolare: 526.008

Ref: 10-F077791

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

CAS: 14647-23-5

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%

Formula: (C₆H₅)₂PCH₂CH₂P(C₆H₅)₂NiCl₂

Purezza: 99%

Colore e forma: orange xtl.

Peso molecolare: 528.04

Ref: 08-28-0030

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

CAS: 14647-23-5

Bis-diphenylphosphinoethane nickel dichloride is a compound that is used for the preparation of other compounds, such as phosphine ligands. Bis-diphenylphosphinoethane nickel dichloride is a solid form of nickel chloride with two crystalline polymorphs, one with a monoclinic crystal structure and the other with a tetragonal crystal structure. In order to obtain the desired product, it must be prepared in an orientational process and synthesised at low temperatures. Bis-diphenylphosphinoethane nickel dichloride has been shown to have anti-cancer properties.br>br> Bis-diphenylphosphinoethane nickel dichloride has also been used to prepare other compounds by cross coupling reactions. This method is effective for preparing compounds that are difficult to make using conventional methods, such as organometallic complexes.br>br> Bis-d

Formula: C₂₆H₂₄Cl₂NiP₂

Purezza: Min. 95%

Peso molecolare: 528.02 g/mol

Ref: 3D-FB60935