CAS 14694-95-2: Cloruro di tris(trifenilfosfina)rodio(I)

Descrizione: Cloruro di tris(trifenilfosfina)rodio(I), comunemente noto come Rh(PPh₃)₃Cl, è un complesso di coordinazione che presenta rodio in uno stato di ossidazione +1. Questo composto è caratterizzato dal coordinamento di tre ligandi di trifenyfosfina (PPh₃) a un atomo centrale di rodio, insieme a un ion cloruro. Appare tipicamente come un solido di colore rosso scuro a viola ed è solubile in solventi organici come il diclorometano e il toluene. La presenza dei voluminosi ligandi di trifenyfosfina conferisce un significativo ingombro sterico, influenzando la reattività e la stabilità del complesso. Rh(PPh₃)₃Cl è noto per le sue proprietà catalitiche, in particolare nella sintesi organica e nelle reazioni di idrogenazione, dove facilita il trasferimento di idrogeno a substrati insaturi. Inoltre, mostra interessanti proprietà fotofisiche, rendendolo oggetto di studio nella chimica di coordinazione e nella catalisi. La sua sintesi spesso implica la reazione di sali di rodio con trifenyfosfina in presenza di una fonte di cloruro.

Formula: C₅₄H₄₅ClP₃Rh

InChI: InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI key: InChIKey=IXAYKDDZKIZSPV-UHFFFAOYSA-M

SMILES: [Cl-][Rh+]([P](C=1C=CC=CC1)(C=2C=CC=CC2)C=3C=CC=CC3)([P](C=4C=CC=CC4)(C=5C=CC=CC5)C=6C=CC=CC6)[P](C=7C=CC=CC7)(C=8C=CC=CC8)C=9C=CC=CC9

Sinonimi:

• (SP-4-2)-Chlorotris(triphenylphosphine)rhodium
• Chlororhodium, Triphenylphosphane
• Chlorotris(Triphenylphosphine)Rhodate (I)
• Chlorotris(Triphenylphosphine)Rhodium
• Chlorotris(Triphenylphosphine)Rhodium(I)
• Decarbon
• Nsc 124140
• Phosphine, Triphenyl-, Chloride, Rhodium Salt (3:1)
• Rhodium Tris(Triphenyl-Phosphine)Chloride
• Rhodium tris(triphenylphosphine) chloride
• Rhodium(I) Tris(Triphenylphosphine) Chloride
• Rhodium(I) Tris(Triphenylphosphine) Chloride Polymer Supported, Wilkinsons Catalyst Polymer Supported
• Rhodium, chlorotris(triphenylphosphine)-
• Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-
• Tris(Tripehnylphosphine)Rhodium(I)Chloride
• Tris(Triphenylphosphine)Rhodium(1) Chloride
• Tris(Triphenylphosphine)Rhodium(I) Chloride Polymer Bound
• Tris(triphenylphosphin)rhodium(I)chlorid
• Tris(triphenylphosphine)chlororhodium
• Tris(triphenylphosphine)chlororhodium(I)
• Tris(triphenylphosphine)rhodium chloride
• Tris(triphenylphosphine)rhodium monochloride
• Wilkinson Catalyst
• Wilkinson's catalyst
• Wilkinson's complex
• Wilkinsons catalyst
• [Tristriphenylphosphine)Rhodium(I) Chloride]
• chlorure de tris(triphenylphosphine)rhodium (I)
• cloruro de tris(trifenilfosfina)rodio (I)
• tris(triphenylphosphine)rhodium i chloride

Tris(triphenylphosphine)rhodium(I) Chloride

CAS: 14694-95-2

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: >98.0%(T)
• Colore e forma: Orange to Brown to Dark red powder to crystal
• Peso molecolare: 925.23

Chlorotris(triphenylphosphine)rhodium(I), 97%

CAS: 14694-95-2

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation …

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: 97%
• Peso molecolare: 925.23

Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-

CAS: 14694-95-2

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: 98%
• Colore e forma: Solid
• Peso molecolare: 925.2149

Tris(triphenylphosphine)rhodium(I) chloride

CAS: 14694-95-2

• Purezza: 98+%
• Colore e forma: Solid
• Peso molecolare: 925.21g/mol

Tris(triphenylphosphine)rhodium(I) chloride, 98%

CAS: 14694-95-2

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. …

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: 98%
• Colore e forma: Red-brown to brown, Crystalline powder
• Peso molecolare: 925.23

Chlorotris(triphenylphosphine)rhodium(I)

CAS: 14694-95-2

• Purezza: 97.0%
• Colore e forma: Solid
• Peso molecolare: 925.22998046875

Tris(triphenylphosphine)rhodium(I) chloride, 99.99%, (trace metal basis)

CAS: 14694-95-2

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. …

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: 99.99%
• Colore e forma: Brown, Crystalline powder
• Peso molecolare: 925.23

Tris(triphenylphosphine)rhodium(I) chloride, 99.95% (metals basis)

CAS: 14694-95-2

• Formula: (C₆H₅)₃PRhCl
• Peso molecolare: 925.23

Tris(triphenylphosphine)rhodium(I) Chloride

CAS: 14694-95-2

Applications Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze …

• Formula: C₅₄H₄₅ClP₃Rh
• Colore e forma: Neat
• Peso molecolare: 925.21

Tris(triphenylphosphine)rhodium(I) chloride

CAS: 14694-95-2

Homogeneous hydrogenation catalyst

• Formula: C₅₄H₄₅ClP₃Rh
• Purezza: Min. 95%
• Colore e forma: Powder
• Peso molecolare: 925.21 g/mol

Chlorotris(triphenylphosphine)rhodium(I), 99% WILKINSON'S CATALYST

CAS: 14694-95-2

• Formula: RhCl(P(C₆H₅)₃
• Purezza: 99%
• Colore e forma: maroon xtl.
• Peso molecolare: 925.23

Polymer-bound chlorotris(triphenylphosphine)rhodium(I) on styrene-divinylbenzene copolymer (20% cross-linked)

CAS: 14694-95-2

• Colore e forma: maroon beads; 20-60 mesh