CAS 15629-92-2

Dicloro[1,1′-(1,3-propanedienil)bis[1,1-difenilfosfina-κP]]nichel

Descrizione:

Dicloro[1,1′-(1,3-propanedienil)bis[1,1-difenilfosfina-κP]]nichel, con il numero CAS 15629-92-2, è un composto di coordinazione che presenta un centro di nichel coordinato a due ligandi di difenilfosfina e due ioni cloruro. Questo composto è caratterizzato dai suoi ligandi di fosfina bidentati, che ne migliorano la stabilità e la reattività. La presenza del collegamento 1,3-propanodile fornisce una struttura unica che influenza l'arrangiamento spaziale dei ligandi attorno all'atomo di nichel. Tipicamente, i complessi di nichel come questo mostrano una geometria quadrata piana, comune per i complessi di nichel(II). I ligandi di difenilfosfina contribuiscono alle proprietà elettroniche del complesso, rendendolo potenzialmente utile nella catalisi e nella sintesi organica. Inoltre, la solubilità e la reattività del composto possono variare a seconda del solvente e delle condizioni, rendendolo un argomento di interesse nella chimica di coordinazione e nella scienza dei materiali. Devono essere adottate precauzioni di sicurezza quando si maneggia questo composto, poiché potrebbe presentare rischi per la salute tipici dei composti organofosforati.

Formula: C₂₇H₂₆Cl₂NiP₂

InChI: InChI=1/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key: InChIKey=ZBQUMMFUJLOTQC-UHFFFAOYSA-L

SMILES: [Cl-][Ni+2]1([Cl-])[P](CCC[P]1(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Sinonimi:

• 1,3-Bis(diphenylphosphino)nickel dichloride
• 1,3-Bis(diphenylphosphino)propane dichloronickel
• 1,3-Bis(diphenylphosphino)propane nickel chloride
• 1,3-Bis(diphenylphosphino)propanenickel dichloride
• Bis[1,3-bis(diphenylphosphino)propane]dichloronickel
• DPPP.NiCl2
• Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel
• Dichloro[1,3-Bis-(diphenylphosphino)propane] nickel(Ⅱ)
• Dichloro[1,3-bis(diphenylphosphino)propane]nickel
• Dichloronickel-Propane-1,3-Diylbis(Diphenylphosphane) (1:1)
• Nickel 1,3-bis(diphenylphosphino)propane dichloride
• Nickel, dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine-κP]]-
• Nickel, dichloro[1,3-propanediylbis[diphenylphosphine]-P,P′]-
• Nickel, dichloro[trimethylenebis[diphenylphosphine]]-
• Phosphine, 1,3-propanediylbis[diphenyl-, nickel complex
• [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
• [1,3-Bis(diphenylphosphino)propane]nickel(II)Dichloride
• [Bis(diphenylphosphino)propane]nickel dichloride
• 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
• 1,3-Bis(Diphenylphosphino)Propane nickel(II)Chloride
• 1,3-bis(diphenylphosphino)propane nickel ii chloride
• 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE
• NiCl2(DPPP)NiCl2(DPPP)
• Dichloro[1,3-Bis-(Diphenylphos
• NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE
• DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE
• 1,3-Bis(dipenylphosphino)propanenickel(II) chloride
• 1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride
• Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%
• 1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN-
• 1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99%
• 1.3-Bis(dipheny phosphine) propane nickel(II)chloride
• (1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purezza: >98.0%(T)

Colore e forma: Orange to Brown to Dark red powder to crystal

Peso molecolare: 542.05

Ref: 3B-B1313

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS: 15629-92-2

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythi

Formula: C₂₇H₂₆Cl₂NiP₂

Colore e forma: Orange to red, powder

Peso molecolare: 542.04

Ref: 02-030167

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

CAS: 15629-92-2

1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%

Formula: (C₆H₅)₂PCH₂CH₂CH₂P(C₆H₅)₂NiCl₂

Purezza: 99%

Colore e forma: red xtl.

Peso molecolare: 542.08

Ref: 08-28-0080

1,3-Bis(diphenylphosphino)propane nickel(II)chloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purezza: 98%

Colore e forma: Solid

Peso molecolare: 542.0423

Ref: IN-DA0032I0

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

CAS: 15629-92-2

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Formula: Cl₂Ni·C₂₇H₂₆P₂

Purezza: 98%

Colore e forma: red solid

Peso molecolare: 542.04g/mol

Ref: 54-OR70169

1,3-Bis(diphenylphosphino)propane-nickel (II) chloride

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Peso molecolare: 542.03

Ref: 7W-GK3219

1,3-Bis(diphenylphosphino)propanedichloronickel II

CAS: 15629-92-2

Formula: C₂₇H₂₆Cl₂NiP₂

Purezza: 95%

Colore e forma: Solid

Peso molecolare: 540.024

Ref: 10-F044623

[1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride

Prodotto controllato

CAS: 15629-92-2

Applications [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins.
References Li, J., et al.: J. Polym. Res., 19, 1-9 (2012); Yamamoto, T., et al.: Tetrahedron Lett., 42, 8653-8656 (2001);

Formula: C₂₇H₂₆Cl₂NiP₂

Colore e forma: Neat

Peso molecolare: 542.04

Ref: TR-B430353