CAS 167316-27-0

(1S,2S)-(+)-N-(4-Toluenosulfonil)-1,2-difeniletilendiamina

Descrizione:

(1S,2S)-(+)-N-(4-Toluenosulfonil)-1,2-difeniletilendiamina è un composto organico chirale noto per il suo ruolo come ligando nella sintesi asimmetrica e nella catalisi. Questa sostanza presenta una struttura di dipheniletilendiamina, che contribuisce alla sua capacità di formare complessi stabili con ioni metallici, aumentando la sua utilità in varie reazioni chimiche. La presenza del gruppo toluenesulfonile aumenta la sua solubilità nei solventi organici e fornisce un sito per ulteriori funzionalizzazioni. Come ligando chirale, può facilitare reazioni enantioselettive, rendendolo prezioso nella sintesi di prodotti farmaceutici e sostanze chimiche fine. Il composto è tipicamente caratterizzato dal suo punto di fusione, solubilità nei solventi organici e rotazione ottica specifica, che riflette la sua natura chirale. Le sue applicazioni si estendono a campi come la chimica medicinale e la scienza dei materiali, dove aiuta nello sviluppo di nuovi composti con proprietà stereochimiche desiderate. I dati di sicurezza devono essere consultati per la manipolazione e lo stoccaggio, come con qualsiasi sostanza chimica.

Formula: C₂₁H₂₂N₂O₂S

InChI: InChI=1/C21H22N2O2S/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17/h2-15,20-21,23H,22H2,1H3/p+1/t20-,21-/m0/s1

Sinonimi:

• (S,S)-TsDPEN
• (1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine
• N-((1S,2S)-2-amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide
• (1S,2S)-2-{[(4-methylphenyl)sulfonyl]amino}-1,2-diphenylethanaminium
• (1S, 2S)-(+)-N-(4-TOLUENE SULFONYL)1,2-DIPHENYL-1,2-ETHANE DIAMINE
• (S,S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE
• (1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE
• (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
• (1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine,98%(S,S)-TsDPEN
• (1S,2S)-(+)-N-(4-TOLUENESULPHONYL)-1,2-DIPHENYLETHYLENEDIAMINE
• (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE (S,S)-TSDPEN
• (1S,2S)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENE-1,2-DIAMINE
• (1S,2S)-N-P-TOSYL-1,2-DIPHENYLETHYLENE-D
• (1S,2S)-(+)-N-(4-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE
• (1S,2S)-TSDPEN
• (1S,2S)-(-)-N-P-TOSYL-1,2-DIPHENYLETHYLENEDIAMINE 98%
• (S,S)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE

(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide

CAS: 167316-27-0

Formula: C₂₁H₂₂N₂O₂S

Purezza: >98.0%(T)

Colore e forma: White to Light yellow powder to crystal

Peso molecolare: 366.48

Ref: 3B-A1699

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

CAS: 167316-27-0

Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The orig

Formula: C₂₁H₂₃N₂O₂S

Colore e forma: White, crystalline powder

Peso molecolare: 367.49

Ref: 02-H27006

(1S,2S)-(+)-N-(4-toluene­sulfonyl)-1,2-diphenyl­ethylenediamine, 98% (S,S)-TsDPEN

CAS: 167316-27-0

(1S,2S)-(+)-N-(4-toluenesulfonyl)-1,2-diphenylethylenediamine, 98% (S,S)-TsDPEN

Formula: C₂₁H₂₂N₂O₂S

Purezza: 98%

Colore e forma: white xtl.

Peso molecolare: 366.48

Ref: 08-07-2370

Benzenesulfonamide, N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methyl-

CAS: 167316-27-0

Formula: C₂₁H₂₂N₂O₂S

Purezza: 95%

Colore e forma: Solid

Peso molecolare: 366.4766

Ref: IN-DA00HZ6F

(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine

CAS: 167316-27-0

Formula: C₂₁H₂₂N₂O₂S

Purezza: ≥ 99.0%

Colore e forma: White powder

Peso molecolare: 366.48

Ref: 7W-GX0129

(1S,2S)-(+)-N-(4-Toluenesulphonyl)-1,2-diphenylethylenediamine

CAS: 167316-27-0

Purezza: 98.0%

Colore e forma: Solid

Peso molecolare: 366.4800109863281

Ref: 10-F012700

(1S,2S)-(+)-N-(4-Toluenesulphonyl)-1,2-diphenylethylenediamine

CAS: 167316-27-0

(1S,2S)-(+)-N-(4-Toluenesulphonyl)-1,2-diphenylethylenediamine

Formula: C₂₁H₂₂N₂O₂S

Purezza: 98%

Colore e forma: off-white solid

Peso molecolare: 366.48g/mol

Ref: 54-OR315018

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

Prodotto controllato

CAS: 167316-27-0

Applications (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is used as a catalyst in the synthesis of keramamine C, a carboline alkaloid that is isolated from the Okinawan sponge Amphimedon sp. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is also used as a catalyst in the synthesis of Tolvaptan (T536650), a selective oral vasopressin V2-receptor agonist that is used to treat hyponatremia.
References Hu, J., et al.: Alkaloid. New York-Acad. Press, 60, 207 (2003); Ishiyama, H., et al.: Heterocycles, 86, 1009 (2012); Schrier, R., et al.: New Engl. J. Med., 355, 2099 (2006); Yin, L., et al.: Tetrahedron-Assymetr., 21, 2390 (2010)

Formula: C₂₁H₂₂N₂O₂S

Colore e forma: Neat

Peso molecolare: 366.48

Ref: TR-T535930