CAS 27607-77-8

Trimetilsilil trifluorometanosulfonato

Descrizione:

Trimetilsilil trifluorometanosulfonato, con il numero CAS 27607-77-8, è un composto chimico che funge da potente agente sililante e da reagente nella sintesi organica. È caratterizzato dal suo gruppo trifluorometano, che ne aumenta la reattività, rendendolo utile in varie trasformazioni chimiche, in particolare nella protezione di alcoli e ammine. Il composto è tipicamente un liquido incolore o giallo pallido con un odore pungente ed è noto per la sua alta volatilità. Trimetilsilil trifluorometanosulfonato è solubile in solventi organici come il diclorometano e l'acetonitrile, ma è meno solubile in acqua. È altamente reattivo e può idrolizzarsi in presenza di umidità, rilasciando acido trifluoroacetico, che è un acido forte. A causa della sua reattività, deve essere maneggiato con cura, utilizzando misure di sicurezza appropriate per evitare il contatto con la pelle e gli occhi, così come l'inalazione di vapori. Le sue applicazioni si estendono a settori come la chimica dei polimeri, dove può facilitare la sintesi di molecole e materiali complessi.

Formula: C₄H₉F₃O₃SSi

InChI: InChI=1/C18H3F35O6/c19-2(1-54,8(26,27)28)55-15(46,47)4(22,10(32,33)34)57-17(50,51)6(24,12(38,39)40)59-18(52,53)7(25,13(41,42)43)58-16(48,49)5(23,11(35,36)37)56-14(44,45)3(20,21)9(29,30)31/h54H,1H2

InChI key: InChIKey=FTVLMFQEYACZNP-UHFFFAOYSA-N

SMILES: S(O[Si](C)(C)C)(C(F)(F)F)(=O)=O

Sinonimi:

• Methanesulfonate, Trimethylsilyl Trifluoro-
• Methanesulfonic acid, 1,1,1-trifluoro-, trimethylsilyl ester
• Silanol, trimethyl-, trifluoromethanesulfonate
• TMSOTf
• Trifluorometanosulfonato De Trimetilsililo
• Trifluoromethanesulfonate de trimethylsilyle
• Trifluoromethanesulfonic acid trimethylsilyl ester
• Trimethylsilanol trifluoromethanesulfonate
• Trimethylsilyl Trifluoromethanesulphonate
• Trimethylsilyl trfluoromethanesulfonate
• Trimethylsilyl triflate
• Trimethylsilyl trifluoromethanesulfonate
• Trimethylsilyl trifluoromethylsulfonate
• Trimethylsilyltrifluormethansulfonat
• Trimethylsilyl trifluoromethylsulphonate
• Methanesulfonic acid, trifluoro-, trimethylsilyl ester
• Trimethylsilyltrifluoromethanesulfonate
• trimethyl-(trifluoromethylsulfonyloxy)silane
• trifluoro-methanesulfonicacitrimethylsilylester
• Methanesulfonicacid,trifluoro-,trimethylsilylester
• Trimethylsllytrifluoromethanesulphonate
• Trimethylsilyltrifluoromethanesulfonate,Anti-Tumor
• CT3795
• trimethylsilyl-trifluoromethansulfonate
• TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE 99%
• Trifluormethansulfonicanhydrid
• TMS TRIFLATE
• SILANE TMS-TRIFLATE

Trimethylsilyl Trifluoromethanesulfonate

CAS: 27607-77-8

Formula: C₄H₉F₃O₃SSi

Purezza: >98.0%(T)

Colore e forma: Colorless to Light yellow to Light orange clear liquid

Peso molecolare: 222.25

Ref: 3B-T0871

Trimethylsilyl trifluoromethanesulfonate, 99%

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their en

Formula: C₄H₉F₃O₃SSi

Purezza: 99%

Colore e forma: Clear, colorless to pale yellow or pale pink, Liquid

Peso molecolare: 222.25

Ref: 02-A12535

Trimethylsilyl trifluoromethanesulfonate, min. 97%

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulfonate, min. 97%

Formula: CF₃SO₃Si(CH₃)₃

Purezza: min. 97%

Colore e forma: colorless liq.

Peso molecolare: 222.26

Ref: 08-14-8600

Trimethylsilyl trifluoromethanesulphonate

CAS: 27607-77-8

Trimethylsilyl trifluoromethanesulphonate

Formula: C₄H₉F₃O₃SSi

Purezza: 98%

Colore e forma: clear. dark yellow to very dark yellow liquid

Peso molecolare: 222.25816g/mol

Ref: 54-PC7867

Trimethylsilyl trifluoromethanesulphonate

CAS: 27607-77-8

S20400 - Trimethylsilyl trifluoromethanesulphonate

Formula: C₄H₉F₃O₃SSi

Purezza: 98%

Colore e forma: Liquid, Clear

Peso molecolare: 222.25

Ref: 10-S20400

Trifluoromethanesulfonic acid trimethylsilyl ester

CAS: 27607-77-8

Used in a Dieckmann-like cyclization of ester-imides and diesters

Formula: C₄H₉F₃O₃SSi

Purezza: Titration Min. 98%

Colore e forma: Yellow Clear Liquid

Peso molecolare: 222.26 g/mol

Ref: 3D-FT03406

Trimethylsilyl trifluoromethane sulfonate

CAS: 27607-77-8

Trimethylsilyl trifluoromethane sulfonate (TMSOTf) is a versatile building block for the synthesis of complex organic compounds. It is a reagent and an intermediate for the production of other fine chemicals and speciality chemicals. TMSOTf is mainly used as a catalyst in organic reactions, such as the Suzuki-Miyaura reaction. TMSOTf can be used to synthesize pharmaceuticals, agrochemicals, and other important chemical products. This compound has been shown to be useful in the construction of synthetic scaffolds that are found in many drug molecules.

Formula: C₄H₉F₃O₃SSi

Peso molecolare: 222.26 g/mol

Ref: 3D-T-6700

TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE 5-GAL DRUM

CAS: 27607-77-8

Trimethylsilyl Blocking Agent
Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.
Trimethylsilyltrifluoromethanesulfonate; Trimethylsilyltriflate; TMSOTf
Strong silylating agent for C- or O-silylationsReacts with nitroalkanes to give N,N-bis(trimethylsiloxy)enaminesNafion SAC-13 has been shown to be a recyclable catalyst for the trimethylsilylation of primary, secondary, and tertiary alcohols in excellent yields and short reaction timesSummary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure

Formula: C₄H₉F₃O₃SSi

Colore e forma: Straw Liquid

Peso molecolare: 222.25

Ref: 3H-SIT8620.0