![Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fcas-image%2Fthumb-webp%2F307584-rhodium-1-bis-1256-e-15-cyclooctadiene-tetrafluoroborate-1-1-1.webp&w=3840&q=75)
CAS 35138-22-8
:Rodio(1+), bis[(1,2,5,6-η)-1,5-ciclooctadiene]-, tetrafluoroborato(1-) (1:1)
Descrizione:
Rodio(1+), bis[(1,2,5,6-η)-1,5-cicloottadiene]-, tetrafluoroborato(1-) è un composto di coordinazione che presenta rodio in uno stato di ossidazione +1, complessato con due molecole di cicloottadiene, che è un dieno che può coordinarsi ai metalli in modo η^4. L'anione tetrafluoroborato funge da controione, fornendo stabilità al complesso. Questo composto è caratterizzato dalla sua geometria unica e dalle proprietà elettroniche, che derivano dall'interazione tra il centro di rodio e i ligandi di cicloottadiene. La presenza dell'ione tetrafluoroborato contribuisce alla sua solubilità in solventi polari. I complessi di rodio sono spesso studiati per le loro proprietà catalitiche, in particolare nella sintesi organica e nelle reazioni di idrogenazione. La struttura specifica di questo composto consente schemi di reattività interessanti e potenziali applicazioni nella catalisi. Inoltre, la stabilità e la reattività del composto possono essere influenzate da fattori come temperatura, solvente e la presenza di altri ligandi o substrati. In generale, questo composto esemplifica la ricca chimica associata ai complessi di metalli di transizione.
Formula:C16H24Rh·BF4
InChI:InChI=1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1
InChI key:InChIKey=NBGSCPNNKGVTKU-UHFFFAOYSA-N
SMILES:[Rh+]123456([CH]7=[CH]1CC[CH]2=[CH]3CC7)[CH]8=[CH]4CC[CH]5=[CH]6CC8.[B+3]([F-])([F-])([F-])[F-]
Sinonimi:- (1Z,5Z)-cycloocta-1,5-diene
- 1,5-Cyclooctadiene, rhodium complex
- Bis(1,5-Cyclooctadien)Rhodium(I) Tetrafluoroborate
- Bis(1,5-Cyclooctadiene)Rhodium Tetrafluoroborate
- Bis(1,5-cyclooctadiene)(tetrafluoroborato)rhodium
- Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate
- Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate(1-)
- Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
- Bis(1,5-cyclooctadienyl)rhodium tetrafluoroborate
- Bis(Cycloocta-1,5-Dien)Rhodium(I)-Tetrafluoroborate
- Bis(cis,cis-1,5-cyclooctadiene)rhodium tetrafluoroborate
- Bis(cyclooctadiene)rhodium tetrafluoroborate
- Bis(cyclooctadiene)rhodium(1+) tetrafluoroborate
- Bis(cyclooctadiene)rhodium(1+) tetrafluoroborate(1-)
- Bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium tetrafluoroborate(1-)-
- Bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(1+) tetrafluoroborate(1-)
- Borate(1-), tetrafluoro-, bis[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(1+)
- Dicyclooctadienerhodium tetrafluoroborate
- Rh(COD)<sub>2</sub>BF<sub>4</sub>
- Rhodium(+1) Cation
- Rhodium(1+), bis(1,5-cyclooctadiene)-, tetrafluoroborate(1-)
- Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-)
- Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)
- Rhodium(I) Tetrafluoroborate 1,5-Cyclooctadiene Complex
- Tetrafluoroborate
- Bis(1,5-Cyclooctadiene) Rhodium(I) Tetrafluoroborate
- Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
- Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%
- Vedi altri sinonimi
Ordinare per
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8 prodotti.
Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
CAS:Formula:C16H24BF4RhColore e forma:Orange to Amber to Dark red powder to crystalPeso molecolare:406.08Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:<p>Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an impo</p>Formula:C16H24BF4RhPeso molecolare:406.08Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+%
CAS:<p>Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+%</p>Formula:Rh(C8H12)2BF4Purezza:98+%Colore e forma:red-brown solidPeso molecolare:406.07Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:Formula:C16H24BF4RhPurezza:97%Colore e forma:SolidPeso molecolare:406.0719Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
CAS:Formula:Rh(C8H12)2BF4Colore e forma:Red to brown solidPeso molecolare:406.08Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
CAS:Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroboratePurezza:95%Colore e forma:PowderPeso molecolare:406.07g/molBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:Formula:C16H24BF4RhPurezza:97%Colore e forma:Solid, No data available.Peso molecolare:406.08Bis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate
CAS:Bis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate (BODIPY) is a catalyst that enhances the rate of hydrosilylation reactions. This catalyst has been shown to be effective in the synthesis of aryl chlorides from amines and aldehydes with high enantioselectivity. BODIPY is also immobilized on silica gel to create an active catalyst for asymmetric synthesis. The immobilization process on silica gel is done by reacting BODIPY with ammonium formate and amines. The resulting catalyst can be used for the synthesis of functionalized organic compounds, such as pyrrolidines, tetrahydrofurans, and thiophenes.Formula:C16H24BF4RhPurezza:Min. 95%Peso molecolare:406.07 g/mol
