CAS 73183-34-3

Bis(pinacolato)diborano

Descrizione:

Bis(pinacolato)diborano, comunemente noto come B2pin2, è un composto organoboro caratterizzato dalla sua struttura e reattività uniche. Presenta due atomi di boro, ciascuno legato a un gruppo pinacolato, derivato dal pinacol, un diolo. Questo composto è tipicamente un liquido incolore o giallo pallido ed è noto per la sua stabilità in condizioni ambientali, rendendolo un reagente prezioso nella sintesi organica, in particolare nella formazione di composti contenenti boro. B2pin2 è spesso utilizzato in reazioni di accoppiamento incrociato, come l'accoppiamento Suzuki-Miyaura, grazie alla sua capacità di fungere da fonte di boro. La sua reattività può essere attribuita alla presenza degli atomi di boro, che possono subire varie trasformazioni, inclusa l'ossidazione e la coordinazione con altri nucleofili. Inoltre, Bis(pinacolato)diborano è solubile in comuni solventi organici, aumentando la sua utilità in contesti di laboratorio. Devono essere osservate precauzioni di sicurezza quando si maneggia questo composto, poiché può essere infiammabile e può comportare rischi per la salute se inalato o ingerito.

Formula: C₁₂H₂₄B₂O₄

InChI: InChI=1S/C12H24B2O4/c1-9(2)10(3,4)16-13(15-9)14-17-11(5,6)12(7,8)18-14/h1-8H3

InChI key: InChIKey=IPWKHHSGDUIRAH-UHFFFAOYSA-N

SMILES: CC1(C)OB(OC1(C)C)B2OC(C)(C)C(C)(C)O2

Sinonimi:

• 1,3,2-Dioxaborolane, bimol. deriv.
• 2,2′-Bi-1,3,2-dioxaborolane, 4,4,4′,4′,5,5,5′,5′-octamethyl-
• 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• 4,4,4',4',5,5,5',5'-Octamethyl-2,2'-Bi-1,3,2-Dioxaborolane
• 4,4,4′,4′,5,5,5′,5′-Octamethyl-2,2′-bi(1,3,2-dioxaborolane)
• 4,4,4′,4′,5,5,5′,5′-Octamethyl-2,2′-bi-1,3,2-dioxaborolan
• 4,4,4′,4′,5,5,5′,5′-Octamethyl-2,2′-bi-1,3,2-dioxaborolane [B₂(pin)₂]
• 4,4,4′,4′,5,5,5′,5′-Octamethyl-2,2′-bis(1,3,2-dioxaborolane)
• 4,4,5,5,4′,4′,5′,5′-Octamethyl-2,2′-Bi(1,3,2-Dioxaborolane)
• 4,4,5,5,4′,4′,5′,5′-Octamethyl-2,2′-bis(1,3,2-dioxaborolane)
• 4,4,5,5,4′,4′,5′,5′-Octamethyl-[2,2′]bi[[1,3,2]dioxaborolanyl]
• 4,4,5,5-Tetramethyl-1,3,2-dioxaborane
• 4,4,5,5-Tetramethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolane
• 4,4,5,5-Tetramethyl-2-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolan
• 4,4,5,5-Tetramethyl-2-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolane
• 4,4′,5,5′-Octamethyl-2,2′-bi-1,3,2-dioxaborolane
• B₂Pin₂
• Bis(2,2,3,3-Tetramethyl-2,3-Butanedionato)Diboron
• Bis(4,4,5,5-tetramethyl-[1,3]dioxolan-2-yl)borane
• Bis(pinacolate)diboron
• Bis(pinacolato) diborate
• Bis(pinacolato)diborane
• Bis(pinacolato)diborane(4)
• Bis(pinanolato)diboron
• Bis-pinacoldiboron
• Bispinacolatodiboronmin
• Diboron Pinacol Ester
• Dipinacoldiboron
• Octamethyl-2,2′-bi(1,3,2-dioxaborolane)
• Pinacol diborane

Bis(pinacolato)diboron

CAS: 73183-34-3

Formula: C₁₂H₂₄B₂O₄

Purezza: >99.0%(GC)

Colore e forma: White to Almost white powder to crystal

Peso molecolare: 253.94

Ref: 3B-B1964

Bis(pinacolato)diboron, 98+%

CAS: 73183-34-3

Bis(pinacolato)diboron is a reagent used for the cis-vicinal diborylation of acetylenes and olefins with platinum catalysis. It acts as a substrate used in a new palladium-catalyzed cyclization of 1,6-enynes leading to homoallylic alkylboronates. It is used as a condensation agent in the preparation

Formula: C₁₂H₂₄B₂O₄

Purezza: 98+%

Colore e forma: White to pale cream, Lumps and/or powder

Peso molecolare: 253.94

Ref: 02-L16088

Bis(Pinacolato)Diboron

CAS: 73183-34-3

Formula: C₁₂H₂₄B₂O₄

Purezza: 98%

Colore e forma: Solid

Peso molecolare: 253.9386

Ref: IN-DA0034J4

Bis(pinacolato)diboron

CAS: 73183-34-3

Bis(pinacolato)diboron

Formula: C₁₂H₂₄B₂O₄

Purezza: 99%

Colore e forma: white crystalline solid

Peso molecolare: 253.93855g/mol

Ref: 54-OR5456

Bis(pinacolato)diboron

CAS: 73183-34-3

Formula: C₁₂H₂₄B₂O₄

Purezza: ≥ 99.0%

Colore e forma: White or off-white crystalline powder or crystals

Peso molecolare: 253.94

Ref: 7W-GK6469

Bis(pinacolato)diboron

CAS: 73183-34-3

Formula: C₁₂H₂₄B₂O₄

Purezza: 99.0%

Colore e forma: Solid

Peso molecolare: 253.94

Ref: 10-F019250

Bis(pinacolato)diboron

CAS: 73183-34-3

Formula: C₁₂H₂₄B₂O₄

Purezza: 99%

Colore e forma: Solid

Peso molecolare: 253.94

Ref: FT-D6878

Bis(pinacolato)diboron, 99%

CAS: 73183-34-3

Bis(pinacolato)diboron, 99%

Formula: C₁₂H₂₄B₂O₄

Purezza: 99%

Colore e forma: white to off-white xtl.

Peso molecolare: 253.94

Ref: 08-05-0030

Bis(pinacolato)diboron

CAS: 73183-34-3

Bis(pinacolato)diboron is a versatile reagent that is used in organic synthesis. It is a boron-containing compound that inhibits the reaction between amines and hydroxide solutions, forming an intermediate copper complex with a carbonyl group. The mechanism of this inhibition has been explored and found to be due to the presence of a hydroxyl group on the bis(pinacolato)diboron molecule. Bis(pinacolato)diboron reacts with an amine to form an adduct containing a boron-nitrogen double bond. This intermediate then reacts with hydroxide ions from the solution to form the final product, which contains both an amine and hydroxyl groups. The isolated yield of this reaction is typically low, but can be increased by using palladium as a catalyst.

Formula: C₁₂H₂₄B₂O₄

Purezza: Min. 98 Area-%

Colore e forma: Powder

Peso molecolare: 253.94 g/mol

Ref: 3D-FB01225

Bis(pinacolato)diboron

CAS: 73183-34-3

Applications Bis(pinacolato)diboron is used as a condensation agent in the preparation poly(arylene)s. Bis(pinacolato)diboron is an organoboranate with potential use as matrix metallo-proteinase (MMP-2) inhibitor.
References Ali, H.A. et al.: Arch. Pharm., 337, 183 (2004); Izumi, A. et al.: Chem. Lett., 7, 728 (2000);

Formula: C₁₂H₂₄B₂O₄

Colore e forma: White To Off-White

Peso molecolare: 253.94

Ref: TR-B522770

Bis(pinacolato)diboron

CAS: 73183-34-3

Bis(pinacolato)diboron is a reagent and building block in organic chemistry. It is a high-quality, versatile building block that can be used as a reactant or intermediate. This compound is used to synthesize complex compounds and fine chemicals. Bis(pinacolato)diboron has been shown to be an effective catalyst for the polymerization of ethylene oxide and propylene oxide, which are important precursors for polyurethanes and polyesters. The high quality of this compound makes it an excellent starting material for the synthesis of other compounds with similar properties.

Formula: C₁₂H₂₄B₂O₄

Purezza: Min. 99 Area-%

Peso molecolare: 253.94 g/mol

Ref: 3D-Q-200724