(R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

CAS: 135616-40-9

Rif. TR-B431500

Informazioni sul prodotto

• Nome: (R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
• Sinonimi: (1R,2R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, (R,R)-2,2'-[(1,2-Cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di(tert-butyl)phenol], 2,2'-[(1R,2R)-1,2-Cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenol
• Marchio: TRC

Descrizione

Applications (R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a versatile ligand used in the preparation of Jacobsen's catalyst.
References Jacobsen, E.N. et al.: J. Am. Chem. Soc., 113, 7063 (1991); Deng, L. et al.: J. Org. Chem., 57, 4320 (1992);

Proprietà chimiche

• Peso molecolare: 546.83
• Formula: C₃₆H₅₄N₂O₂
• Colore/Forma: Neat
• InChI: InChI=1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m1/s1
• InChI key: InChIKey=FGIQYENVFXNDTF-REPODWTJSA-N
• SMILES: CC(C)(C)C1=C/C(=C/N[C@@H]2CCCC[C@H]2N/C=C2\C=C(C(C)(C)C)C=C(C(C)(C)C)C2=O)C(=O)C(C(C)(C)C)=C1