Diethyl acetone-1,3-dicarboxylate, 96%

CAS: 105-50-0

Ref. 02-A10933

Product Information

• Name: Diethyl acetone-1,3-dicarboxylate, 96%
• Synonyms: 1,5-diethyl 3-oxopentanedioate, 1,3-Acetonedicarboxylic Acid Diethyl Ester, 1,3-Acetonedicarboxylicaciddiethylester Diethyl3-oxoglutarate, 1,5-Diethyl 3-oxopentanedioate, 3-Oxo-Pentanedioic Aci Diethyl Ester, 3-Oxo-Pentanedioicacidiethyl Ester, 3-Oxopentanedioic acid diethyl ester, Acetone-1,3-dicarboxylic acid diethyl ester, Diethyl 1,3-Acetonedicarboxylate；Diethyl 3-Oxoglutarate, Diethyl 1,3-acetone dicarboxylate, Diethyl 1,3-acetonedicarboxylate, Diethyl 2-oxopropane-1,3-dicarboxylate, Diethyl 3-ketoglutarate, Diethyl 3-oxoglutarate, Diethyl 3-oxopentanedioate, Diethyl Acetylpropanedioate, Diethyl acetone-1,3-dicarboxylate, Diethyl acetonedicarboxylate, Diethyl β-ketoglutarate, Diethyl β-oxoglutarate, Diethyl-1,3-Acetonedicarboxyalte, Diethyl-3-oxo-pentanedionate, Diethyl1,3-Acetonedicarboxylate, Diethylacetone dicarboxylate, Glutaric acid, 3-oxo-, diethyl ester, Glutaric acid, β-oxo-, diethyl ester, NSC 9013, Pentanedioic acid, 3-oxo-, 1,5-diethyl ester, Pentanedioic acid, 3-oxo-, diethyl ester, β-Ketoglutaric acid diethyl ester
• CAS: 105-50-0

Description

Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Brand: Alfa Aesar By Thermo Fisher Scientific

Chemical properties

• Molecular weight: 202.21
• Formula: C₉H₁₄O₅
• Purity: 96%
• Color/Form: Clear colorless, Liquid
• InChI: InChI=1S/C9H14O5/c1-3-13-8(11)5-7(10)6-9(12)14-4-2/h3-6H2,1-2H3
• InChI key: ZSANYRMTSBBUCA-UHFFFAOYSA-N
• SMILES: CCOC(=O)CC(=O)CC(=O)OCC